Given two unital C*-algebras equipped with states and a positive operator in the enveloping von Neumann algebra of their minimal tensor product, we define three parameters that measure the capacity of the operator to align with a coupling of the two given states. Further, we establish a duality formula that shows the equality of two of the parameters for operators in the minimal tensor product of the relevant C*-algebras. In the context of abelian C*-algebras, our parameters are related to quantitative versions of Arveson's null set theorem and to dualities considered in the theory of optimal transport. On the other hand, restricting to matrix algebras we recover and generalize quantum versions of Strassen's theorem. We show that in the latter case our parameters can detect maximal entanglement and separability.
