We experimentally investigate the flow through a hollow cube, with an indoor ground-level passive scalar source, immersed in a rough-wall turbulent boundary layer inside a water tunnel. The focus is on characterizing scalar transport within the cube, through simultaneous scalar and flow measurements using planar laser-induced fluorescence and particle image velocimetry. To understand the role of window positioning, three cube configurations, labelled as ‘centre’, ‘up-down’ and ‘down-up’, distinguished by window positions at the upstream and downstream ends, are studied. Varying window position alters the flow characteristics within the cube, resulting in differences in scalar concentration and distribution. The steady-state concentration is highest for ‘centre’, followed by ‘up-down’ and ‘down-up’ configurations. Regarding the scalar distribution, ‘centre’ showed accumulation near the top and bottom walls, while ‘up-down’ and ‘down-up’ exhibited scalar buildup in the lower and upper half of the cube, respectively. The flow patterns and scalar transport mechanisms remained consistent across different Reynolds numbers ($Re=U_{Ref}H/\nu = 20\ 000$, 35 000, 50 000) for each configuration; $U_{Ref}=$ incoming flow velocity at cube height ($H$), and $\nu =\,$ kinematic viscosity of water. The analysis is extended by revising the classical box model, accounting for practical complexities such as non-perfect mixing. Our results can help better understand and model indoor–outdoor pollutant exchange in complex urban environments.

The deformation of fluid elements governs many processes in porous media, including the transport, dispersion and mixing of solutes, chemical reactions and colloidal particles. Recently, it has been shown that even in strongly heterogeneous porous media, steady three-dimensional (3-D) Darcy flow with isotropic hydraulic conductivity admits only constrained kinematics. This is due to its inherently helicity-free nature, as the velocity is everywhere orthogonal to the vorticity. This property precludes braided streamlines and instead admits a pair of coherent 3-D streamfunctions, and the streamlines cannot wander freely throughout the flow domain. In this study, we consider the impact of these kinematic constraints upon fluid deformation at the Darcy scale. We show that the helicity-free condition corresponds to an orthogonal 3-D streamline coordinate system, which we use to derive an ab initio continuous time random walk framework for fluid deformation. We find that the helicity-free condition combined with the intermittent nature of shear events leads to fluid deformation that is limited to algebraic growth, with stretching ranging from sublinear to superlinear behaviour. Fluid deformation in 3-D isotropic Darcy flow is remarkably similar to that of two-dimensional (2-D) Darcy flow, and the structure of 3-D Darcy flow is fundamentally the same as two superposed 2-D Darcy flows. These results have implications for understanding flow and transport in heterogeneous porous media, and provide a basis for quantification of mixing and dispersion in isotropic 3-D Darcy flow.

We explore the interior stratification that develops in a reservoir of fluid in which there is a localised source of destabilising (positive) buoyancy and a distributed source of stabilising (negative) buoyancy at the surface of the fluid, combined with an interior turbulent diffusivity. The source of destabilising buoyancy forms a descending turbulent plume that entrains ambient fluid, and this, coupled with the interior turbulent diffusivity, leads to mixing of the interior fluid. When the ratio $Pe$ of the plume source volume flux to the diffusive flux across the whole reservoir is large, the reservoir is well mixed except for a narrow surface boundary layer, while for smaller $Pe$, the reservoir is more stratified, consistent with the results of Hughes et al. (J. Fluid Mech., vol. 581, 2007, pp. 251–276) and Hughes & Griffiths (Annu. Rev. Fluid Mech., vol. 40, issue 1, 2008, pp. 185–208). We explore the evolution of the system when the source buoyancy flux varies in time, exploring both sudden changes and oscillatory changes in the forcing. Provided that the time scale of the change in the forcing is comparable to or smaller than the response time of the reservoir, as the source buoyancy flux decreases the plume may become trapped in the upper part of the reservoir, leading to a much shallower mixed zone. However, in the case of a source whose strength oscillates in time, as the source buoyancy flux increases, again the deeper water becomes involved in the mixing and circulation. We discuss briefly how these results may provide insight into the impact of changes in the forcing on mixing in deep ocean waters.

The composition of the Earth's mantle, built by impacts of metallic core planetesimals, depends on the time offered to metal–silicate equilibration (concentration equalization by mixing) as the impactor fragments settle down. Smaller fragments equilibrate while bigger ones remain segregated and accumulate in the – therefore iron rich – Earth's core. To understand the primary instability setting the interpenetration depth and wavelength between the impactor and the mantle, Lherm et al. (J. Fluid Mech., vol. 937, 2022, A20) analyse the intermingled phenomena occurring when a drop impacts a substrate of a pool of another liquid, digging a crater. The density difference between the phases triggers a Rayleigh–Taylor instability when the drop is denser than the pool. The overall planet chemical composition relies on a tradeoff between fragmentation and mixing; this study provides elements to decipher their relative importance.

We conduct a well-controlled model experiment for a wide variety of canopy flows. Examples of these include engineering flows such as wind flow, dispersion of scalars through and over urban areas, and the convective heat transfer in many heat exchangers, as well as natural canopies such as flows through terrestrial or aquatic vegetation. We aim to shed the light on fundamental flow and transport phenomena common to these applications. Specifically, the characteristics of mean flow and scalar concentration characteristics of a turbulent boundary layer flow impinging on a canopy, which comprises a cluster of tall obstacles (this can also be interpreted as a porous obstruction). The cluster is created with a group of cylinders of diameter $d$ and height $h$ arranged in a circular patch of diameter $D$. The solidity of the patch/obstruction is defined by $\phi$ (the total planar area covered by cylinders), which is systematically varied ($0.098 \leq \phi \leq 1$) by increasing the number of cylinders in a patch ($N_c$). A point source is placed at ground level upstream of the patch and its transport over and around the patch is examined. Time-averaged velocity and scalar fields, obtained from simultaneous planar particle image velocimetry-planar laser-induced fluorescence (PIV-PLIF) measurements, reveal that the characteristics of wake and flow above porous patches are heavily influenced by $\phi$. In particular, we observe that the horizontal and vertical extent of the wake and scalar concentration downstream of the patches decreases and increases with $\phi$, respectively. Here, the recirculation bubble is shifted closer to the trailing edge (TE) of the patches as $\phi$ increases, limiting the flow from convecting downstream, decreasing the scalar concentration and virtually ‘extending’ the patch in the streamwise direction. As the bubble forms in the TE, vertical bleeding increases and hence the concentration increases above the patch where the cylinders appear to ‘extend’ vertically towards the freestream.

When a liquid drop strikes a deep pool of a target liquid, an impact crater opens while the liquid of the drop decelerates and spreads on the surface of the crater. When the density of the drop is larger than the target liquid, we observe mushroom-shaped instabilities growing at the interface between the two liquids. We interpret this instability as a spherical Rayleigh–Taylor instability due to the deceleration of the interface, which exceeds the ambient gravity. We investigate experimentally the effect of the density contrast and the impact Froude number, which measures the importance of the impactor kinetic energy to gravitational energy, on the instability and the resulting mixing layer. Using backlighting and planar laser-induced fluorescence methods, we obtain the position of the air–liquid interface, an estimate of the instability wavelength, and the thickness of the mixing layer. We derive a model for the evolution of the crater radius from an energy conservation. We then show that the observed dynamics of the mixing layer results from a competition between the geometrical expansion of the crater, which tends to thin the layer, and entrainment related to the instability, which increases the layer thickness. The mixing caused by this instability has geophysical implications for the impacts that formed terrestrial planets. Extrapolating our scalings to planets, we estimate the mass of silicates that equilibrates with the metallic core of the impacting bodies.

We consider miscible displacements in two-dimensional homogeneous porous media where the displacing fluid is less viscous and has a different density than the displaced fluid. We find that the dynamics evolve through nine possible regimes depending on the viscosity ratio, strength of density variations and the strength of the background flow, as characterized by the Péclet number. At early times the interface is dominated by longitudinal diffusion before undergoing a transition to a slumping regime where vertical flow is important. At intermediate times, vertical flow and diffusion can be neglected and there are three different limiting solutions: a fingering limit; an injection-driven gravity-current limit; and a density-driven gravity-current limit. Finally at late times, transverse diffusion becomes important and there is a transition from an apparent shutdown regime to a viscously enhanced Taylor-slumping regime. In each of the regimes, the dominant scalings are identified and reduced-order models for the evolution of the concentration field are developed. Lastly, three case studies are considered to illustrate the dominant physical balances in the geophysically relevant setting of geological $\textrm {CO}_2$ storage.

We present a numerical study on how tidal force and topography influence flow dynamics, transport and mixing in horizontal convection. Our results show that local energy dissipation near topography will be enhanced when the tide is sufficiently strong. Such enhancement is related to the height of the topography and increases as the tidal frequency $\omega$ decreases. The global dissipation is found to be less sensitive to the changes in $\omega$ when the latter becomes small and asymptotically approaches a constant value. We interpret the behaviour of the dissipation as a result of the competition among the dominant forces in the system. According to which mechanism prevails, the flow state of the system can be divided into three regimes, which are the buoyancy-, tide- and drag-control regimes. We show that the mixing efficiency $\eta$ for different tidal energy and topography height can be well described by a universal function $\eta \approx \eta _{HC}/(1+\mathcal {R})$, where $\eta _{HC}$ is the mixing efficiency in the absence of tide and $\mathcal {R}$ is the ratio between tidal and available potential energy inputs. With this, one can also determine the dominant mechanism at a certain ocean region. We further derive a power law relationship connecting the mixing coefficient and the tidal Reynolds number.

We present a new, simple and physically motivated parameterization, based on the ratio of Thorpe and Ozmidov scales, for the irreversible turbulent flux coefficient $\varGamma _{\mathcal {M}}= {\mathcal {M}}/\epsilon$, i.e. the ratio of the irreversible rate ${\mathcal {M}}$ at which the background potential energy increases in a stratified flow due to macroscopic motions to the dissipation rate of turbulent kinetic energy $\epsilon$. Our parameterization covers all three key phases (crucially, in time) of a shear-induced stratified turbulence life cycle: the initial, ‘hot’ growing phase, the intermediate energetically forced phase and the final ‘cold’ fossilization decaying phase. Covering all three phases allows us to highlight the importance of the intermediate one, to which we refer as the ‘Goldilocks’ phase due to its apparently optimal (and so neither too hot nor too cold, but just right) balance, in which energy transfer from background shear to the turbulent mixing is most efficient. The value of $\varGamma _{\mathcal {M}}$ is close to 1/3 during this phase, which we demonstrate appears to be related to an adjustment towards a critical or marginal Richardson number for sustained turbulence ${\sim }0.2\text {--}0.25$. Importantly, although buoyancy effects are still significant at leading order for the turbulent dynamics during this intermediate phase, the marginal balance in the flow ensures that the turbulent mixing of the (density) scalar is nevertheless effectively ‘locked’ to the turbulent mixing of momentum. We present supporting evidence for our parameterization through comparison with six oceanographic datasets that span various turbulence generation regimes and a wide range of geographical location and depth. Using these observations, we highlight the significance of parameterizing an inherently variable flux coefficient for capturing the turbulent flux associated with rare energetic, yet fundamentally shear-driven (and so not strongly stratified) overturns that make a disproportionate contribution to the total mixing. We also highlight the importance of representation of young turbulent patches in the parameterization for connecting the small scale physics to larger scale applications of mixing such as ocean circulation and tracer budgets. Shear-induced turbulence is therefore central to irreversible mixing in the world's oceans, apparently even close to the seafloor, and it is critically important to appreciate the inherent time dependence and evolution of mixing events: history matters to mixing.

The meridional component of the earth's rotation is often neglected in geophysical contexts. This is referred to as the ‘traditional approximation’ and is justified by the typically small vertical velocity and aspect ratio of such problems. Ocean fronts are regions of strong horizontal buoyancy gradient and are associated with strong vertical transport of tracers and nutrients. Given these comparatively large vertical velocities, non-traditional rotation may play a role in governing frontal dynamics. Here the effects of non-traditional rotation on a front in turbulent thermal wind balance are considered using an asymptotic approach. Solutions are presented for a general horizontal buoyancy profile and examined in the simple case of a straight front. Non-traditional effects are found to depend strongly on the direction of the front and may lead to the generation of jets and the modification of the frontal circulation and vertical transport.

We explore the strong stratification regime of stably stratified turbulence and the intermediate regime towards the viscosity-affected stratified state. Three-dimensional velocity-density fields from direct numerical simulations are decomposed into internal gravity waves (IGWs) and eddy motion based on Riley's decomposition (Riley et al., AIP Conf. Proc., vol. 76, issue 1, 1981, pp. 79–112) extended to account for the space–time properties of waves, their modification by vertically sheared horizontal flow and the vertical mixing by eddies (Lam et al., Atmosphere, vol. 11, issue 4, 2020, p. 420). We establish the evolution equations for the IGW and eddy parts separately. Up to buoyancy Reynolds number ${Re}_b\sim 1$, we observe a large exchange of energy that pumps energy from the IGW to eddy. For ${Re}_b>1$, the IGW and eddy dynamics seem to be separate and no global exchange is observed. Our decomposition enables computation of the contributions to the mixing coefficient in terms of the IGW and eddy. At the largest ${Re}_b$ considered, the mixing due to eddies is four times that due to waves.

Oceanic mesoscale currents (‘eddies’) can have significant effects on the distributions of passive tracers. The associated inhomogeneous and anisotropic eddy fluxes are traditionally parametrised using a transport tensor ($K$-tensor), which contains both diffusive and advective components. In this study, we analyse the eddy transport tensor in a quasigeostrophic double-gyre flow. First, the flow and passive tracer fields are decomposed into large- and small-scale (eddy) components by spatial filtering, and the resulting eddy forcing includes an eddy tracer flux representing advection by eddies and non-advective terms. Second, we use the flux-gradient relation between the eddy fluxes and the large-scale tracer gradient to estimate the associated $K$-tensors in their entire structural, spatial and temporal complexity, without making any additional assumptions or simplifications. The divergent components of the eddy tracer fluxes are extracted via the Helmholtz decomposition, which yields a divergent tensor. The remaining rotational flux does not affect the tracer evolution, but dominates the total tracer flux, affecting both its magnitude and spatial structure. However, in terms of estimating the eddy forcing, the transport tensor prevails over its divergent counterpart because of the significant numerical errors induced by the Helmholtz decomposition. Our analyses demonstrate that, in general, the $K$-tensor for the eddy forcing is not unique, that is, it is tracer-dependent. Our study raises serious questions on how to interpret and use various estimates of $K$-tensors obtained from either observations or eddy-resolving model solutions.

Darcy's law is used widely to model flow in heterogeneous porous media via a spatially varying conductivity field. The isotropic Darcy equation imposes significant constraints on the allowable Lagrangian kinematics of the flow field and thus upon scalar transport. These constraints stem from the fact that the helicity density in these flows is identically zero and so the flow does not admit closed or knotted flow paths. This implies that steady Darcy flow possesses a particularly simple flow topology which involves streamlines that do not possess closed orbits, knots or linked vortex lines. This flow structure is termed ‘complex lamellar’ and consists of fully integrable (in the dynamical systems sense) streamlines which admit two analytic constants of motion and so preclude chaotic advection. In this study we show that these constants of motion correspond to a pair of streamfunctions which are single valued and topologically planar, and the intersections of the level sets of these invariants correspond to streamlines of the flow. We show that the streamfunctions and iso-potential surfaces of the flow form a semi-orthogonal coordinate system, that naturally recovers the topological constraints imposed on the Lagrangian kinematics of these flows. We use this coordinate system to investigate the impact of these constraints upon the kinematics of Darcy flow, including the deformation of fluid elements and transverse macrodispersion of solutes in the absence of local dispersion. These results shed new light on the relevance and limitations of isotropic Darcy flow as a model of transport, mixing and reaction in porous media.

A Lagrangian experimental study of an axisymmetric turbulent water jet is performed to investigate the highly anisotropic and inhomogeneous flow field. Measurements are conducted within a Lagrangian exploration module, an icosahedron apparatus, to facilitate optical access of three cameras. Stereoscopic particle tracking velocimetry results in three-component tracks of position, velocity and acceleration of the tracer particles within the vertically oriented jet with a Taylor-based Reynolds number ${\textit {Re}}_\lambda \simeq 230$. Analysis is performed at seven locations from 15 diameters up to 45 diameters downstream. Eulerian analysis is first carried out to obtain critical parameters of the jet and relevant scales, namely the Kolmogorov and large (integral) scales as well as the energy dissipation rate. Lagrangian statistical analysis is then performed on velocity components stationarised following methods inspired by Batchelor (J. Fluid Mech., vol. 3, 1957, pp. 67–80), which aim to extend stationary Lagrangian theory of turbulent diffusion by Taylor to the case of self-similar flows. The evolution of typical Lagrangian scaling parameters as a function of the developing jet is explored and results show validation of the proposed stationarisation. The universal scaling constant $C_0$ (for the Lagrangian second-order structure function), as well as Eulerian and Lagrangian integral time scales, are discussed in this context. Constant $C_0$ is found to converge to a constant value (of the order of $C_0 = 3$) within 30 diameters downstream of the nozzle. Finally, the occurrence of finite particle size effects is investigated through consideration of acceleration-dependent quantities.

We conduct an asymptotic analysis to derive a macrotransport equation for the long-time transport of a chemotactic/diffusiophoretic colloidal species in a uniform circular tube under a steady, laminar, pressure-driven flow and transient solute gradient. The solute gradient drives a ‘log-sensing’ advective flux of the colloidal species, which competes with Taylor dispersion due to the hydrodynamic flow. We demonstrate excellent agreement between the macrotransport equation and direct numerical solution of the full advection–diffusion equation for the colloidal species transport. In addition to its accuracy, the macrotransport equation requires $O(10^3)$ times less computational runtime than direct numerical solution of the advection–diffusion equation. Via scaling arguments, we identify three regimes of the colloidal species macrotransport, which span from chemotactic/diffusiophoretic-dominated macrotransport to the familiar Taylor dispersion regime, where macrotransport is dominated by the hydrodynamic flow. Finally, we discuss generalization of the macrotransport equation to channels of arbitrary (but constant) cross-section and to incorporate more sophisticated models of chemotactic fluxes. The macrotransport framework developed here will broaden the scope of designing chemotactic/diffusiophoretic transport systems by elucidating the interplay of macrotransport due to chemotaxis/diffusiophoresis and hydrodynamic flow.

We study the reactive displacement of two miscible fluids in channel flows and establish a quantitative link between fluid stretching and chemical reactivity. At the mixing interface, the two fluids react according to the instantaneous irreversible bimolecular reaction $A + B \rightarrow C$. We simulate the advection–diffusion–reaction problem using a random walk based reactive particle method that is free of numerical dispersion. The relative contributions of stretching and diffusion to mixing-limited reaction is controlled by changing the Péclet number, and the channel roughness is also systematically varied. We observe optimal ranges of fluid stretching that maximize reactivity, which are captured by a Lagrangian stretching measure based on an effective time period that honours the stretching history. We show that the optimality originates from the competition between the enhanced mixing by fluid stretching and the mass depletion of the reactants. We analytically derive the spatial distribution of reaction products using a lamellar formulation and successfully predict the optimal ranges of fluid stretching, which are consistent across different levels of channel roughness. These findings provide a mechanistic understanding of how the interplay between fluid stretching, diffusion and channel roughness controls mixing-limited reactions in rough channel flows, and show how reaction hot spots can be predicted from the concept of optimal fluid stretching.

The interaction of fluids with surface-mounted obstacles in canopy flows leads to strong turbulence that dominates dispersion and mixing in the neutrally stable atmospheric surface layer. This work focuses on intermittency in the Lagrangian velocity statistics in a canopy flow, which is observed in two distinct forms. The first, small-scale intermittency, is expressed by non-Gaussian and not self-similar statistics of the velocity increments. The analysis shows an agreement in comparison with previous results from homogeneous isotropic turbulence (HIT) using the multifractal model, extended self-similarity and velocity increments’ autocorrelations. These observations suggest that the picture of small-scale Lagrangian intermittency in canopy flows is similar to that in HIT and, therefore, they extend the idea of universal Lagrangian intermittency to certain inhomogeneous and anisotropic flows. Second, it is observed that the root mean square of energy increments along Lagrangian trajectories depends on the direction of the trajectories’ time-averaged turbulent velocity. Subsequent analysis suggests that the flow is attenuated by the canopy drag while leaving the structure function's scaling unchanged. This observation implies the existence of large-scale intermittency in Lagrangian statistics. Thus, this work presents a first empirical evidence of intermittent Lagrangian velocity statistics in a canopy flow that exists in two distinct senses and occurs due to different mechanisms.

Bedload particle hops are defined as successive motions of a particle from start to stop, characterizing one of the most fundamental processes of bedload sediment transport in rivers. Although two transport regimes have been recently identified for short and long hops, respectively, there is still the lack of a theory explaining the mean hop distance–travel time scaling for particles performing short hops, which dominate the transport and may cover over 80 % of the total hop events. In this paper, we propose a velocity-variation-based formulation, the governing equation of which is intrinsically identical to that of Taylor dispersion for solute transport within shear flows. The key parameter, namely the diffusion coefficient, can be determined by hop distances and travel times, which are easier to measure and more accurate than particle accelerations. For the first time, we obtain an analytical solution for the mean hop distance–travel time relation valid for the entire range of travel times, which agrees well with the measured data. Regarding travel times, we identify three distinct regimes in terms of different scaling exponents: respectively, $\sim$1.5 for the initial regime and $\sim$5/3 for the transition regime, which define the short hops, and 1 for the Taylor dispersion regime defining long hops. The corresponding distribution of the hop distance is analytically obtained and experimentally verified. We also show that the conventionally used exponential distribution, as proposed by Einstein, is solely for long hops. Further validation of the present formulation is provided by comparing the simulated accelerations with measurements.

Micro- and nanodroplets have many important applications such as in drug delivery, liquid–liquid extraction, nanomaterial synthesis and cosmetics. A commonly used method to generate a large number of micro- or nanodroplets in one simple step is solvent exchange (also called nanoprecipitation), in which a good solvent of the droplet phase is displaced by a poor one, generating an oversaturation pulse that leads to droplet nucleation. Despite its crucial importance, the droplet growth resulting from the oversaturation pulse in this ternary system is still poorly understood. We experimentally and theoretically study this growth in Hele-Shaw-like channels by measuring the total volume of the oil droplets that nucleate out of it. In order to prevent the oversaturated oil from exiting the channel, we decorated some of the channels with a porous region in the middle. Solvent exchange is performed with various solution compositions, flow rates and channel geometries, and the measured droplets volume is found to increase with the Péclet number, $Pe$, with an approximate effective power law $V\propto Pe^{0.50}$. A theoretical model is developed to account for this finding. With this model we can indeed explain the $V\propto Pe^{1/2}$ scaling, including the prefactor, which can collapse all data of the ‘porous’ channels onto one universal curve, irrespective of channel geometry and composition of the mixtures. Our work provides a macroscopic approach to this bottom-up method of droplet generation and may guide further studies on oversaturation and nucleation in ternary systems.

The spatial distribution of a scalar undergoing advection and diffusion is impacted by the velocity variability sampled by tracer particles. In spatially structured velocity fields, such as porous medium flows, Lagrangian velocities along streamlines are often characterized by a well-defined correlation length and can thus be described by spatial-Markov processes. Diffusion, on the other hand, is generally modelled as a temporal process, making it challenging to capture advective and diffusive dynamics in a single framework. We develop a description of transport based on a spatial-Markov velocity process along Lagrangian particle trajectories, incorporating the effect of diffusion as a local averaging process in velocity space. The impact of flow structure on this diffusive averaging is quantified through an effective shear rate. The latter is fully determined by the point statistics of velocity magnitudes together with characteristic longitudinal and transverse length scales associated with the flow field. For infinite longitudinal correlation length, our framework recovers Taylor dispersion, and in the absence of diffusion it reduces to a standard spatial-Markov velocity model. We derive dynamical equations governing the evolution of particle position and velocity and obtain scaling laws for the dependence of longitudinal dispersion on Péclet number. These results provide new insights into the role of shear and diffusion on dispersion processes in heterogeneous media.