Mineralogical studies were performed on authigenic clay minerals of mudrocks, sandstones, and bentonites from 38 boreholes in the Late Permian coal measures of the Bowen Basin. Clay-mineral separations of samples from the northern Bowen Basin consist mainly of (Reichweite, R) R = 1 and R ≥ 3 interstratified illite-smectite (I-S), chlorite, and kaolinite. In the southern Bowen Basin, samples from higher stratigraphie sections are characterized by randomly ordered (R = 0) I-S mixed layers, and kaolinite and chlorite in smaller amounts. Samples from the lower sections consist of (R ≥ 3) I-S, chlorite, chlorite-rich chlorite-smectite (C-S), and laumontite.

Examination of the mineralogy and distribution of authigenic clay minerals from the Late Permian coal measures in the northern part of the Bowen Basin indicated that the presence of clay minerals is not systematically related to depth and clay occurrences do not occur regularly. These mineralogical variations of clay in volcaniclastic sediments are incompatible with thermal control. Variations in the rate of fluid flow and potassium supply owing to permeability exert major influences on clay-mineral paragenesis and the reaction of illitization. In more permeable zones (possibly faults or fracture zones), highly illitic clays with lath-shaped morphologies may have precipitated directly from potassium-rich fluids migrating from deeper parts of the basin. In addition, abundant chlorite precipitated contemporaneously with illitic clays, which may have resulted from sufficient magnesium and iron occurring in the fluids as a result of dissolution of intermediate or mafic-rock fragments. At the same time, clay paragenesis with less illitic I-S, kaolinite, and minor chlorite occurs outside the channelized zones of high fluid flow, where a diffusive-flow regime may have predominated with lower ratios of the activities of K+ and H+ (i.e., αK+/αH+) in the solutions.

In the southern Bowen Basin, depth-related changes in the distribution of clay minerals are evident and may be indicative of thermal control on clay-mineral reactions. Zeolites are present locally in the Late Permian volcaniclastic rocks in the southern Bowen Basin, but not in the north. This is attributed to a low ratio of αCO2/αH2O (where α = activity) and/or more saline and alkaline solutions.

Investigation of material from three core sections of the RWTH-1 drill-hole in the Wurm syncline of Aachen, Germany, shows mineralogical and structural evidence of intensive hydrothermal activity in the footwall of the Aachen thrust. Mineral and microstructural data indicate minimum temperatures of 200–250°C. CISillite 001 values of 0.45–0.61 (Δ°2θ) and insignificant amounts of smectite indicate a late diagenetic grade for illite pointing to temperatures <200°C. Chlorite, mainly formed in veins and cleavage planes, has CISchlorite 002 values between 0.35 and 0.26 (Δ°2θ) which only in part point to anchizonal grade. In contrast to these illite and chlorite data, maximum temperatures up to 370°C can be expected based on comparison with recently published fluid inclusion and mineral thermometric data. Illite is neither significantly affected by the hydrothermal event nor by deformation, and mirrors the burial history of the Wurm syncline.

Chlorite grew syntectonically as is shown by bent and predominantly stretched sheets which do not, however, have deformed structures. Syntectonic hydrothermal growth by incipient nucleation along crystal edges limited domainsize and thus also the CISchlorite 002 values. The hydrothermal event did not last long enough to allow further crystal growth. The retarded CISillite and CISchlorite grades can be best explained by limited duration(probably <5000 y) of the hydrothermal event which for a short time reached epithermal temperatures. The hydrothermal fluid flow was caused by dewatering of sedimentary rocks during thrusting and tectonic thickening within the Variscan orogen and it was focused along the Aachen thrust which represents the frontal Variscan thrust.

Orogenic forelands host interactions between deformation and static or migrating fluids. Given their accessibility and dimensions, these areas are not only historic landmarks for structural geology, but they are also areas of prime interest for georesource exploration and geological storage, and loci of potential geohazards. Geochemical techniques applied on cements filling tectonic structures and associated trapped fluids can constrain the temperature, pressure, origin and pathways of fluids during deformation and allow the characterization of the past fluid system. In this review focused on calcite cements, we first present and critically discuss the most used geochemical techniques to appraise specific parameters of the fluid system. Second, we summarize the outcomes of selected case studies where the past fluid system was reconstructed with consideration of tectonics, either at the scale of the individual fold/thrust or at the scale of the fold-and-thrust belt. At first order, the past fluid system evolves in a similar way with respect to the considered stage of deformation, being rather closed to external fluids when deformation is bounded to mesoscale structure development, and opening to vertical flow when thrust and folds develop. In a more detailed view, it seems that the past fluid system evolves and distributes under the influence of the structural style, of the geometry of the major faults and of the lithology of the sedimentary succession. Through this review, we illustrate the concept of geochemistry-assisted structural geology through case studies where the geochemistry of calcite veins constrained subsurface geometries and structural developments in orogenic forelands.

Hydrofractures, or hydraulic fractures, are fractures where a significantly elevated fluid pressure played a role in their formation. Natural hydrofractures are abundant in rocks and are often preserved as magmatic dykes or sills, and mineral-filled fractures or mineral veins. However, we focus on the formation and evolution of non-igneous hydrofractures. Here we review the basic theory of the role of fluid pressure in rock failure, showing that both Terzaghi’s and Biot’s theories can be reconciled if the appropriate boundary conditions are considered. We next discuss the propagation of hydrofractures after initial failure, where networks of hydrofractures may form or hydrofractures may ascend through the crust as mobile hydrofractures. As fractures can form as a result of both tectonic stresses and an elevated fluid pressure, we address the question of how to ascertain whether a fracture is a hydrofracture. We argue that extensional or dilational fractures that formed below c. 2–3 km depth are, under normal circumstances, hydrofractures, but at shallower depth they may, but must not be hydrofractures. Since veins and breccias are often the products of hydrofractures that are left in the geological record, we discuss these and critically assess which vein structures can, and which do not necessarily, indicate hydrofracturing. Hydrofracturing can suddenly and locally change the permeability in a rock by providing new fluid pathways. This can lead to highly dynamic self-organization of crustal-scale fluid flow.

Faulted and fractured systems form a critical component of fluid flow, especially within low-permeable reservoirs. Therefore, developing suitable methodologies for acquiring structural data and simulating flow through fractured media is vital to improve efficiency and reduce uncertainties in modelling the subsurface. Outcrop analogues provide excellent areas for the analysis and characterization of fractures within the reservoir rocks where subsurface data are limited. Variation in fracture arrangement, distribution and connectivity can be obtained from 2D fractured cliff sections and pavements. These sections can then be used for efficient discretization and homogenization techniques to obtain reliable predictions on permeability distributions in the geothermal reservoirs. Fracture network anisotropy in the Malm reservoir unit is assessed using detailed structural analysis and numerical homogenization of outcrop analogues from an open pit quarry within the Franconian Basin, Germany. Several events are recorded in the fracture networks from the Late Jurassic the Alpine Orogeny and are observed to be influenced by the Kulmbach Fault nearby with a reverse throw of 800 m. The fractured outcrops are digitized for fluid flow simulations and homogenization to determine the permeability tensors of the networks. The tensors show differences in fluid transport direction where fracture permeability is controlled by orientation compared to a constant value. As a result, it is observed that the orientation of the tensor is influenced by the Kulmbach Fault, and therefore faults within the reservoirs at depth should be considered as important controls on the fracture flow of the geothermal system.

Fluids are commonly invoked as the primary cause for weakening of detachment shear zones. However, fluid-related mechanisms such as pressure-solution, reaction-enhanced ductility, reaction softening and precipitation of phyllosilicates are not fully understood. Fluid-facilitated reaction and mass transport cause rheological weakening and strain localization, eventually leading to departure from failure laws derived in laboratory experiments. This study focuses on the Miocene Raft River detachment shear zone in northwestern Utah. The shear zone is localized in the Proterozoic Elba Quartzite, which unconformably overlies the Archaean basement, and consists of an alternating sequence of quartzite and muscovite-quartzite schist. In this study, we characterize fluid-related microstructures to constrain conditions that promoted brittle failure in a plastically deforming shear zone. Thin-section analyses reveal the presence of healed microcracks, transgranular fluid inclusion planes and grain boundary fluid inclusion clusters. Healed microcracks occur in three sets, one sub-perpendicular to the mylonitic foliation, and a set of two conjugate microcracks oriented at ∼40–60° to the mylonitic foliation. Healed microfractures are filled with quartz, which has a distinct fabric, suggesting that microcracks healed while the shear zone was still at conditions favourable for quartz crystal plasticity. Transgranular fluid inclusion planes also occur in three sets, similar in orientation to the healed microfractures. Fluid inclusions commonly decorate grain and subgrain boundaries as inter- and intragranular clusters. Our results document ductile overprint of brittle microstructures, suggesting that, during exhumation, the Raft River detachment shear zone crossed the brittle–ductile transition repeatedly, providing pathways for fluids to permeate through this shear zone.

Radiogenic strontium isotopes (87Sr/86Sr) of vein carbonates play a central role in the tectonometamorphic study of fold-and-thrust belts and accretionary wedges and have been used to document fluid sources and fluxes, for example, along major fault zones. In addition, the 87Sr/86Sr ratios of vein carbonates can trace the diagenetic to metamorphic evolution of pore fluids in accreted sediments. Here we present 87Sr/86Sr ratios of vein carbonates from the Infrahelvetic flysch units of the central European Alps (Glarus Alps, Switzerland), which were accreted to the North Alpine fold-and-thrust belt during the early stages of continental collision. We show that the vein carbonates trace the Sr isotopic evolution of pore fluids from an initial seawater-like signature towards the Sr isotopic composition of the host rock with increasing metamorphic grade. This relationship reflects the progressive equilibration of the pore fluid with the host rock and allows us to constrain the diagenetic to low-grade metamorphic conditions of deformation events, including bedding-parallel shearing, imbricate thrusting, folding, cleavage development, tectonic mélange formation and extension. The strontium isotope systematics of vein carbonates provides new insights into the prograde to early retrograde tectonic evolution of the Alpine fold-and-thrust belt and helps to understand the relative timing of deformation events.

Petrographic study of the Frewens sandstone, Upper Cretaceous Frontier Formation, documents reservoir-scale diagenetic heterogeneity. Iron-bearing calcite cement occurs as large concretions that generally follow bedding and are most common near the top of the sandstone. Median thickness of the concretions is 0.6 m, length 4.5 m, and width 5.7 m; median volume is 5.2 m3. Concretions comprise 12% of the sandstone.

The minus-cement porosity of concretion samples is low, indicating that the calcite precipitated near maximum burial depth. Isotopic and burial history data suggest that the calcite precipitated at ~54°C from evolved meteoric water enriched in 18O or from a mixed meteoric±marine pore-water. Shell-bearing transgressive shales above the Frewens sandstone are interpreted to be the source of calcium carbonate. Concretions of this size and distribution would influence fluid flow in a reservoir and would reduce the amount of hydrocarbons in place.

Variational principles are derived in order to facilitate the investigation of the vibrations and stability of single and double-walled carbon nanotubes conveying a fluid, from a linear time-dependent partial differential equation governing their displacements. The nonlocal elastic theory of Euler-Bernoulli beams takes small-scale effects into account. Hamilton’s principle is obtained for double-walled nano-tubes conveying a fluid. The natural and geometric boundary conditions identified are seen to be coupled and time-dependent due to nonlocal effects.

We establish some interesting duality results for Markov-modulated fluid flow models. Though fluid flow models are continuous-state analogues of quasi-birth-and-death processes, some duality results do differ by the inclusion of a scaling factor.

The Neogene extensional province of southern Tuscany in central Italy provides an outstanding example of fossil and active structurally controlled fluid flow and epithermal ore mineralization associated with post-orogenic silicic magmatism. Characterization of the hydrodynamic regime leading to the genesis of the polysulphide deposit (known as Filone di Boccheggiano) hosted within the damage zone of the Boccheggiano Fault is a key target to assess modes of fossil hydrothermal fluid circulation in the region and, more generally, to provide inferences on fault-controlled hydrothermal fluid flow in extensional settings. We provide a detailed description of the fault zone architecture and alteration/mineralization associated with the Boccheggiano ore deposit and report the results of fluid inclusion and stable oxygen isotope studies. This investigation shows that the Boccheggiano ore consists of an adularia/illite-type epithermal deposit and that sulphide ore deposition was controlled by channelling of hydrothermal fluids of dominantly meteoric origin within the highly anisotropic permeability structure of the Boccheggiano Fault. The low permeability structure of the fault core compartmentalized the fluid outflow preventing substantial cross-fault flow, with focused fluid flow occurring at the hangingwall of the fault controlled by fracture permeability. Fluid inclusion characteristics indicate that ore minerals were deposited between 280° and 350°C in the upper levels of the brittle extending crust (lithostatic pressure in the order of 0.1 GPa). Abundant vapour-rich inclusions in ore-stage quartz are consistent with fluid immiscibility and boiling, and quartz ore vein textures suggest that mineralization in the Boccheggiano ore deposit occurred during cyclic fluid flow in a deformation regime regulated by transient and fluctuating fluid pressure conditions. Results from this study (i) predict a strongly anisotropic permeability structure of the fault damage zone during crustal extension, and (ii) indicate the rate of secondary (structural) permeability creation and maintenance by active deformation in the hangingwall of extensional faults as the major factor leading to effective hydraulic transmissivity in extensional terranes. These features intimately link ore-grade mineralization in extensional settings to telescoping of hydrothermal flow along the hangingwall block(s) of major extensional fault zones.

A study of the décollement zones in the Moffat Shale Group in the Ordovician Northern Belt of the Southern Uplands of Scotland reveals a progressive sequence of deformation and increased channelization of fluid flow. The study concentrates on exposures of imbricated Moffat Shale on the western coast of the Rhins of Galloway. Initial deformation occurred in partially lithified sediments and involved stratal disruption and shearing of the shales. Deformation then became more localized in narrower fault zones characterized by polyphase hydrothermal fluid flow/veining events. Deformation continued after vein formation, resulting in the development of low-temperature crystal plastic microstructures and further veining. Late-stage deformation is recorded as a pressure solution event possibly reflecting the cessation of slip on these faults as the slice became accreted. Most deformation can be ascribed to SE-directed thrusting and incorporation of the individual sheets into the Southern Uplands thrust stack. Later sinistral shear deformation, not observed in overlying turbidites, is also localized in these fault zones. The study reveals the likely structures formed at levels of an accretionary prism deforming under diagenetic to low-grade metamorphic conditions.

The mean busy period of a Markov-modulated queue or fluid model is computed by an extension of the time-reversal argument connecting the steady-state distribution and the maximum of a related Markov additive process.