In our paper, we study multiplicative properties of difference sets $A-A$ for large sets $A \subseteq {\mathbb {Z}}/q{\mathbb {Z}}$ in the case of composite q. We obtain a quantitative version of a result of A. Fish about the structure of the product sets $(A-A)(A-A)$. Also, we show that the multiplicative covering number of any difference set is always small.

Let β>1 be a real number, and let {ak} be an unbounded sequence of positive integers such that ak+1/ak≤β for all k≥1. The following result is proved: if n is an integer with n>(1+1/(2β))a1 and A is a subset of {0,1,…,n} with , then (A+A)∩(A−A) contains a term of {ak }. The lower bound for |A| is optimal. Beyond these, we also prove that if n≥3 is an integer and A is a subset of {0,1,…,n} with , then (A+A)∩(A−A) contains a power of 2. Furthermore, cannot be improved.

Qualified difference sets (QDS) composed of unions of cyclotomic classes are discussed. An exhaustive computer search for such QDS and modified QDS that also possess the zero residue has been conducted for all powers n=4,6,8 and 10. Two new families were discovered in the case n=8 and some new isolated systems were discovered for n=6 and n=10.