Hostname: page-component-848d4c4894-cjp7w Total loading time: 0 Render date: 2024-07-07T14:08:34.902Z Has data issue: false hasContentIssue false
  • English
  • Français

Upgrading of Heavy Oil From The San Joaquin Valley of California by Aqueous Pyrolysis

Published online by Cambridge University Press:  10 February 2011

John G. Reynolds ,
Ann M. Murray ,
Eric V. Nuxoll ,
Glenn A. Fox ,
Charles B. Thorsness  and
M. Rashid Khan
John G. Reynolds
Affiliation:
Lawrence Livermore National Laboratory, University of California, Livermore, CA 94551, [email protected]
Ann M. Murray
Affiliation:
Lawrence Livermore National Laboratory, University of California, Livermore, CA 94551, [email protected]
Eric V. Nuxoll
Affiliation:
Lawrence Livermore National Laboratory, University of California, Livermore, CA 94551, [email protected]
Glenn A. Fox
Affiliation:
Lawrence Livermore National Laboratory, University of California, Livermore, CA 94551, [email protected]
Charles B. Thorsness
Affiliation:
Lawrence Livermore National Laboratory, University of California, Livermore, CA 94551, [email protected]
M. Rashid Khan
Affiliation:
Texaco R & D, P. 0. Box 509, Beacon, NY, 12508-0509
Get access

Abstract

Midway Sunset crude oil and well-head oil were treated at elevated temperatures in a closed system with the presence of water. Mild to moderate upgrading, as measured by increase in API gravity, was observed at 400°C or above. Reduced pressure operation exhibited upgrading activity comparable to upgrading under normal aqueous pyrolysis conditions. Reduced pressure operation was obtained by the use of specific blending methods, a surfactant, and the proper amount of water. The use of metal complexes provided additional upgrading. The best of the minimum set tested was Co(ll) 2-ethylhexanoate. Fe, Zn, Mo, Cu, and Ni complexes also showed some levels of activity.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 432: Symposium S – Aqueous Chemistry and Geochemistry of Oxides , 1996 , 333
Copyright
Copyright © Materials Research Society 1997

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Olsen, D. K., U. S. DOE report DE93000153 (1993).Google Scholar
2. McCollum, J. D. and Quick, L. M., U.S. Patent 3960706 (1976); A. K. S. Murthy, K. M. Patel, and A. Y. Bekker, The Third Unitar/UNDP International Conference on Heavy Crude and Tar Sand, Chapter 122, 1291–1296 (1985 Google Scholar
3. Lewin, M. D., ACS Div. Fuel Chem., Preprints, 37(4), 1545–1547 (1992).Google Scholar
4. Ross, D. S., Jayaweera, I., and Hoogwater, S., ACS Div. Petrol. Chem., Preprints, 353–355 (1994).Google Scholar