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Synthesis, Structural and Optical Characterization of II-VI Semiconductors Included in Sodalite-Type Hosts

Published online by Cambridge University Press:  21 February 2011

K. L. Moran
Affiliation:
Department of Chemistry, University of California, Santa Barbara, CA 93106
W. T. A. Harrison
Affiliation:
Department of Chemistry, University of California, Santa Barbara, CA 93106
T. E. Gier
Affiliation:
Department of Chemistry, University of California, Santa Barbara, CA 93106
J. E. Mac Dougall
Affiliation:
Department of Chemistry, University of California, Santa Barbara, CA 93106
G. D. Stucky
Affiliation:
Department of Chemistry, University of California, Santa Barbara, CA 93106
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Abstract

Solid-state chemistry has been used to control both the size and the interconnection distance of small II-VI semiconductor moeities incorporated in zeolitic hosts with the sodalite-type structure. Structural characterization was carried out using X-ray Rietveld powder methods, and optical properties of these materials were also measured. These novel materials show quantum superlattice effects as evidenced by blue shifts in their optical absorption spectra.

Type
Research Article
Copyright
Copyright © Materials Research Society 1990

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References

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