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On the Origin of the Structural Modulation in the Bi Cuprates As Derived from 3d-Metal Substituted Phases

Published online by Cambridge University Press:  21 February 2011

J. M. Tarascon ,
Y. LePage ,
W. R. McKinnon ,
E. Tselepis ,
P. Barboux ,
B.G. Bagley  and
R. Ramesh
J. M. Tarascon
Affiliation:
Bell Communications Research, Red Bank, NJ 07701.
Y. LePage
Affiliation:
National Research Council of Canada, Ottawa, Canada K1AOR9.
W. R. McKinnon
Affiliation:
National Research Council of Canada, Ottawa, Canada K1AOR9.
E. Tselepis
Affiliation:
National Research Council of Canada, Ottawa, Canada K1AOR9.
P. Barboux
Affiliation:
Bell Communications Research, Red Bank, NJ 07701.
B.G. Bagley
Affiliation:
Bell Communications Research, Red Bank, NJ 07701.
R. Ramesh
Affiliation:
Bell Communications Research, Red Bank, NJ 07701.
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Abstract

A substitution for Cu by a 3d-metal (Fe, Co, Mn) in the superconducting Bi phases (Bi2Sr2Can−1CunOy; n = 1,2 and 3) has led to the discovery of new phases. These 3d-metal substituted phases are non-superconducting and, in contrast to the Cu-based phases, they exhibit a structural modulation that is commensurate. Single crystal x-ray studies were performed on the Bi2Sr3Fe2Oy, Bi2Sr2CoOy and Bi2Sr2MnOy compounds. A result, in common, is that the modulation is caused by the periodic insertion of a row of oxygen atoms in the Bi layers and this results in a corrugated-like slab structure. The Bi-O layers can be described as composed of alternating rocksalt-type and oxygen deficient perovskite-type blocks. For the Fe (n=2) phase the Bi atoms form ribbons (chains) in the ab plane. This is in contrast to the n=1 Co or Mn phases for which a disorder at the oxygen position is observed. Although the extra oxygen in the Bi-O layer could account for the doping mechanism in the high Tc Bi-phases, cation non-stoichiometry may also beimportant.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 156: Symposium M – High Temperature Superconductors: Relationships Between Properties, Structure, and Solid State Chemistry , 1989 , 317
Copyright
Copyright © Materials Research Society 1989

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References

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