Hostname: page-component-586b7cd67f-gb8f7 Total loading time: 0 Render date: 2024-11-25T17:33:02.544Z Has data issue: false hasContentIssue false

GaN On 6H-SiC – Structural And Optical Properties

Published online by Cambridge University Press:  21 February 2011

C. Wetzel
Affiliation:
Physik-Department E16, TU München, 85747 Garching, Germany
D. Volm
Affiliation:
Physik-Department E16, TU München, 85747 Garching, Germany
B. K. Meyer
Affiliation:
Physik-Department E16, TU München, 85747 Garching, Germany
K. Pressel
Affiliation:
Institut für Halbleiterphysik, 15230 Frankfurt/Oder, Germany
S. Nilsson
Affiliation:
Institut für Halbleiterphysik, 15230 Frankfurt/Oder, Germany
E. N. Mokhov
Affiliation:
Ioffe Physico-Technical Institute, 194021 St. Petersburg, Russia
P. G. Baranov
Affiliation:
Ioffe Physico-Technical Institute, 194021 St. Petersburg, Russia
Get access

Abstract

Recent progress in the growth of high quality 6H-SiC single crystals has led to an ideal substrate material for GaN epitaxial films. Nearly matching lattice constants of wurzite GaN to 6H-SiC in the hexagonal plane can reduce strain effects at the interface. We employed the sublimation sandwich method to grow single crystal layers at reasonable growth rates with free carrier concentrations of 2×1017 cm-3. Very sharp x-ray diffraction peaks of the GaN (0002) plane are obtained indicating the high quality of this system (Δ(2θ) < 0.1 degrees). These findings are directly reflected in the optical properties. The photoluminescence is dominated by a single sharp exciton line, impurity related donor acceptor transitions are seen with very weak intensities. However, at lower energies the internal luminescence transitions of the 3d transition metal ions Fe and V are observable. The incorporation of Fe is confirmed by electron paramagnetic resonance.

Type
Research Article
Copyright
Copyright © Materials Research Society 1994

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. For a recent review see: Strite, S. and Morkoc, H., J. Vac. Sci. Technol. B 10, 1237 (1992)Google Scholar
2. Lin, M.E., Sverdlov, B., Zhou, G.L. and Morkoc, H., Appl. Phys. Lett. 62, 3479 (1993)Google Scholar
3. Lin, M.E., Sverdlov, B.N. and Morkoc, H., Appl. Phys. Lett. 63, 3625 (1993)Google Scholar
4. Amano, H., Kito, M., Hiramatsu, K., and Akasaki, I., Jap. J. Appl. Phys. 28, L2112 (1989)Google Scholar
5. Nakamura, S., Senoh, M. and Mukai, T., Jap. J. Appl. Phys. 30, L1708 (1991)Google Scholar
6. Vodakov, Y.A., Karklina, M.I., Mokhov, E.N. and Roenkov, A.D., Inorganic Materials 17, 537 (1980) in russianGoogle Scholar
7. Vodakov, Y.A., Mokhov, E.N., Roenkov, A.D. and Saidbekov, D.T., phys.stat.sol. (a) 51, 209 (1979)Google Scholar
8. Vodakov, Y.A., Mokhov, E.N., Ramm, M.G. and Roenkov, A.D., Kristall und Technik, 14, 729 (1979)Google Scholar
9. Wetzel, C., Volm, D., Meyer, B.K., Pressel, K., Nilsson, S., Mokhov, E.N. and Baranov, P.G., unpublishedGoogle Scholar
10. Lagerstedt, O. and Monemar, B., J. Appl. Phys. 45, 2266 (1974)Google Scholar
11. Ogino, T. and Aoki, M., Jap. J. Appl. Phys. 19, 2395 (1980)Google Scholar
12. Brandt, M.S., Johnson, N.M., Molnar, R.J., Singh, R. and Moustakas, T.D., unpublishedGoogle Scholar
13. Monemar, B., Lagerstedt, O. and Gislason, H.P., J. Appl. Phys. 51, 625 (1980)Google Scholar
14. Pankove, J.I. and Hutchby, J.A., J. Appl. Phys. 47, 5387 (1976)Google Scholar
15. Khan, M.R.H., Ohshita, Y., Sawaki, N. and Akasaki, I., Sol. State Comm. 57, 405 (1986)Google Scholar
16. Baur, J., Maier, K., Kunzer, M., Kaufmann, U., Schneider, J., Amano, H., Akasaki, I., Detchprohm, T. and Hiramatsu, K., Appl. Phys. Lett. 64, 857 1994)Google Scholar
17. Maier, K., Kunzer, M., Kaufmann, U., Schneider, J., Monemar, B., Akasaki, I. and Amano, H., Defects in Semiconductors, ed. by Heinrich, H. and Jantsch, W., Tans. Tech. 1994, Vol. 143–147, p. 93 Google Scholar
18. For a compilation of data see Zunger, A., Solid State Phys. 39, 275 (1987)Google Scholar
19. Clerjaud, B., J. Phys. C 18, 3615 (1987)Google Scholar
20. Kaufmann, U., Ennen, H., Schneider, J., Woerner, R., Weber, J. and Koehl, F., Phys. Rev. B 25, 5598 (1982)Google Scholar
21. Skolnick, M.S., Dean, P.J., Kane, M.J., Uihlein, Ch., Roberts, D.J., Hayes, W., Cockayne, B. and Mac Ewan, W.R., J. Phys. C 16, L767 (1983)Google Scholar