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The NNWSI Waste form Testing Program

Published online by Cambridge University Press:  25 February 2011

V. M. Oversby*
Affiliation:
Department of Earth Sciences, Lawrence Livermore National Laboratory, Livermore, CA 94550
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Abstract

A waste form testing program has been developed to ensure that the release rate of radionuclides from the engineered barrier system will meet NRC and EPA regulatory requirements. Waste form performance testing will be done under unsaturated, low water availability conditions which represent the expected repository conditions. Testing will also be done under conditions of total immersion of the waste form in repository-type water to cover the possibility that localized portions of the repository might contain standing water. Testing of reprocessed waste forms for CHLW and DHLW will use reaction vessels fabricated from Topopah Spring tuff. Chemical elements which are expected to show the highest release rates in the mildly oxidizing environment of the Topopah Spring tuff horizon at Yucca Mountain are Np and Tc. To determine the effect of residual canister material and of corrosion products from the canister/overpack, waste form testing will be done in the presence of these materials. The release rate of all radionuclides which are subject to NRC and EPA regulations will be measured, and the interactive effects of the released radionuclides and the rock reaction vessels will be determined. The testing program for spent fuel will determine the release rate from bare spent fuel pellets and from Zircaloy clad spent fuel where the cladding contains minor defects. A metal testing program for Zircaloy will establish the expected lifetime of the cladding material. Estimation of the state of cladding for fuel presently in reactor pool storage will provide baseline data for Zircaloy containment credit.

Type
Research Article
Copyright
Copyright © Materials Research Society 1984

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References

REFERENCES

1. McCright, R. D., Weiss, H., Juhas, M. C. and Logan, R. W., Lawrence Livermore National Laboratory Report UCRL-89988, 1983.Google Scholar
2. Sass, J. H. and Lachenbruch, A. H., U.S. Geological Survey Open File Report-82, 1982.Google Scholar
3. Oversby, V. M., Lawrence Livermore National Laboratory Report, in preparation, 1984.Google Scholar
4. McVay, G. L. and Robinson, G. R., Battelle Pacific Northwest Laboratories Report PNL-4897, 1983.Google Scholar
5. The unsaturated test method is being developed by John Bates of Argonne National Laboratory. This method will be documented during 1984.Google Scholar
6. Morrow, C. A., Moore, D. E. and Byerlee, J. D., paper in this volume, 1984.Google Scholar
7. This work is being done as part of a cooperative testing program involving NNWSI and Savannah River Laboratory.Google Scholar
8. Woodley, R. E., Hanford Engineering Development Laboratory Report HEDL-TME 83-28, 1983.Google Scholar
8. This work is being conducted by C. N. Wilson at the Hanford Engineering Development Laboratory. The work will be documented in a HEDL-TME report during 1984.Google Scholar