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Enrichment of Uranium inside Wood: a Natural Analog from a Sandstone-hosted Roll-type Uranium Ore Deposit
Published online by Cambridge University Press: 17 March 2011
Abstract
Furniture contaminated with uranium will be disposed of, together with U-bearing waste, in ageological repository such as the WIPP site in New Mexico. It is important to understand the effect of the wooden furniture on the migration of uranium in order to predict long-term behavior of uranium in a geological repository environment. In this paper, we present natural uraninite-bearing carbonized wood pieces from a sandstone-hosted roll-type uranium ore deposit in NW China. Results from SEM and TEM observations show that there are nanometer sized, and micron-sized, uraninite crystals that have accumulated on cell walls of the carbonized wood. Some uranitite crystrals display oval and round shapes that may be the result of microbial-induced reduction of uranium from groundwater. The wood carbonized fragments are the most uranium-rich “phase.” In some areas, aggregates of pyrite crystals occur withthe uraninite. It is proposed that organic components from the decay of the wood cells provide nutrientsfor the anaerobic bacteria to grow. The wood pieces with the bacteria inside may serve as scavengers of uranium because of the local reducing chemical environment.
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- Copyright © Materials Research Society 2004