Hostname: page-component-586b7cd67f-l7hp2 Total loading time: 0 Render date: 2024-11-29T08:56:12.774Z Has data issue: false hasContentIssue false
  • English
  • Français

Ball-milling: an alternative way for the preparation of anodes for lithium-ion batteries

Published online by Cambridge University Press:  11 February 2011

Daniel Guérard  and
Raphaël Janot
Daniel Guérard
Affiliation:
Laboratoire de Chimie du Solide Minéral, UMR 7555 CNRS, UHP Nancy, BP 239, 54506 Vandoeuvre lès Nancy Cedex, France
Raphaël Janot
Affiliation:
Laboratoire de Chimie du Solide Minéral, UMR 7555 CNRS, UHP Nancy, BP 239, 54506 Vandoeuvre lès Nancy Cedex, France
Get access

Abstract

The preparation of new anodic materials for lithium-ion batteries is possible by ball-milling within liquid media. Those powders can be as diverse as: highly anisometric graphite particles (geometrical anisotropy around 100), graphite-maghemite (γ Fe2O3) composites and graphite-intercalation compounds with high lithium contents (e.g. LiC3 is obtained by ball-milling of Li + 2C powders). These phases are the first superdense graphite-lithium compounds stable under ambient pressure and lead to a capacity of 1 Ah/g as primary battery and 370 mAh/g as secondary one. The synthesis and characterizationschemical analysis, XRD, pycnometry, TEM, SEM, 7Li NMR, magnetic measurements) are presented for each materials as well as the electrochemical behavior.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 756: Symposia EE/FF – Solid-State Ionics – Materials for Fuel Cells and Fuel Processors , 2002 , EE8.5
Copyright
Copyright © Materials Research Society 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Poizot, P., Laruelle, S., Grugeon, S., Dupont, L. and Tarascon, J.M., Nature 407, 496 (2000)Google Scholar
2. Lee, Y., Zhang, R. and Liu, Z., Electrochem. & Solid State Let., 3, 167 (2000)Google Scholar
3. Nagaura, T. and Tozawa, K., Prog. Batt. Solar Cells 9, 209 (1990)Google Scholar
4. Janot, R., Conard, J. and Guérard, D., Carbon 40–15, 2887 (2002)Google Scholar
5. Janot, R. and Guérard, D., J. All. Comp. 333/1–2, 302 (2002)Google Scholar
6. Janot, R. and Guérard, D., Carbon 39–12, 1931 (2001)Google Scholar
7. Nalimova, V., Sol. St. Com. 97, 583 (1996)Google Scholar
8. Janot, R., Conard, J. and Guérard, D., Proc. Coll. Mat. Tours (Oct. 2002) CM-14–004Google Scholar
9. Janot, R. and Guérard, D., Proc. Carbon′02, Beijing (Sept. 2002) H062 Google Scholar
10. Bindra, C., Nalimova, V.A., Sklovsky, D.E., Benes, Z. and Fischer, J.E., J. Electroch. Soc. 145, 2377 (1998)Google Scholar