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Understanding Li-O2 Battery Cathode Product Formation via Liquid Cell Electron Microscopy

Published online by Cambridge University Press:  30 July 2020

Saran Pidaparthy
Affiliation:
University of Illinois at Urbana-Champaign, Urbana, Illinois, United States
Chang Liu
Affiliation:
University of Illinois at Urbana-Champaign, Urbana, Illinois, United States
Ryan Stephens
Affiliation:
Shell International Exploration and Production Inc., Houston, Texas, United States
Qian Chen
Affiliation:
University of Illinois at Urbana-Champaign, Urbana, Illinois, United States
Jian-Min Zuo
Affiliation:
University of Illinois at Urbana-Champaign, Urbana, Illinois, United States

Abstract

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Type
In Situ TEM at the Extremes - Liquid environment
Copyright
Copyright © Microscopy Society of America 2020

References

Lu, J., et al. ., “Aprotic and Aqueous Li–O2 Batteries,” Chem. Rev., vol. 114, no. 11, pp. 56115640, Jun. 2014.10.1021/cr400573bCrossRefGoogle Scholar
Ma, Z. et al. ., “A review of cathode materials and structures for rechargeable lithium–air batteries,” Energy Environ. Sci., vol. 8, no. 8, pp. 21442198, 2015.10.1039/C5EE00838GCrossRefGoogle Scholar
Grande, L. et al. ., “The Lithium/Air Battery: Still an Emerging System or a Practical Reality?,” Adv. Mater., vol. 27, no. 5, pp. 784800, Feb. 2015.10.1002/adma.201403064CrossRefGoogle ScholarPubMed
Yang, C. et al. ., “Direct Observations of the Formation and Redox-Mediator-Assisted Decomposition of Li2O2 in a Liquid-Cell Li–O2 Microbattery by Scanning Transmission Electron Microscopy,” Adv. Mater., vol. 29, no. 41, p. 1702752, Nov. 2017.10.1002/adma.201702752CrossRefGoogle Scholar
Hou, C. et al. ., “Operando observations of RuO2 catalyzed Li2O2 formation and decomposition in a Li-O2 micro-battery,” Nano Energy, vol. 47, pp. 427433, 2018.10.1016/j.nanoen.2018.02.057CrossRefGoogle Scholar
Liu, P. et al. ., “Operando characterization of cathodic reactions in a liquid-state lithium-oxygen micro-battery by scanning transmission electron microscopy,” Sci. Rep., vol. 8, no. 1, p. 3134, 2018.Google Scholar
Schneider, N. M., et al. ., “Nanoscale evolution of interface morphology during electrodeposition,” Nat. Commun., vol. 8, no. 1, p. 2174, 2017.10.1038/s41467-017-02364-9CrossRefGoogle ScholarPubMed
Mitchell, R. R., et al. ., “Mechanisms of Morphological Evolution of Li2O2 Particles during Electrochemical Growth,” J. Phys. Chem. Lett., vol. 4, no. 7, pp. 10601064, Apr. 2013.10.1021/jz4003586CrossRefGoogle ScholarPubMed
Funding for this work was provided by the Energy & Biosciences Institute through the EBI-Shell program.Google Scholar