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Transmission Electron Microscopy Study of Planar Defects in Polycrystalline CdTe Thin Films

Published online by Cambridge University Press:  02 July 2020

Y. Yan
Affiliation:
National Renewable Energy Laboratory, Golden, Colorado80401.
K.M. Jones
Affiliation:
National Renewable Energy Laboratory, Golden, Colorado80401.
M.M. Al-Jassim
Affiliation:
National Renewable Energy Laboratory, Golden, Colorado80401.
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Abstract

CdTe is a promising photovoltaic material due to its near optimum band gap and high absorption coefficient. Polycrystalline, thin-film CdTe/CdS solar cells have demonstrated an efficiency of 15.8%. High density of extended defects is often found in polycrystalline CdTe films grown by close-spaced sublimation (CSS). So far, most investigations of defects in CdTe have focused on epitaxially grown films, and the reported extended defects are mainly lamellar twins. However, epitaxially grown films generally have a different microstructure compared to CSS grown polycrystalline CdTe thin films. in this paper, we report our study of extended defects in CSSgrown polycrystalline CdTe thin films by high-resolution transmission electron microscopy (HRTEM). We found that the extended defects are mostly lamellar twins and stacking faults. The stacking faults always propagate across the grains, without ending at a partial dislocation inside the grains.

Type
Semiconductors
Copyright
Copyright © Microscopy Society of America 2001

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