Outputs of suspended sediment and bedload from the 7·7 km2 moorland Monachyle basin and the 6·8 km2, 40%-forested Kirkton basin near Balquhidder, and inputs from tributary streams and mainstream bank erosion, are compared. Sediment yield is about three times higher in the forested basin and varies more sensitively with streamflow, suggesting greater availability of erodible sediment. The output is predominantly of suspended sediment and is derived mainly from tributary streams. Initial observations following partial moorland ploughing and forest clearfelling in 1986 indicate that erosion of timber loading areas and logging roads is the main sediment source.

As part of the joint British-Scandinavian Surface Waters Acidification Programme, the Institute of Hydrology is establishing catchment studies in Scotland. Data from these catchment studies are being used to develop a range of models for investigating short-term and long-term changes in catchment acidity. Information on the modelling techniques available at the Institute of Hydrology is presented together with applications of the models to catchments in Scotland.

Episodes of high streamwater acidity have been cited in the literature as causal in fish-kills; such episodes are often associated with acid precipitation. An investigation utilising continuous monitoring of both precipitation and streamwater for a remote upland site in SW Scotland is reported and the occurrence of two episodes of streamwater acidification is described. The apparent mechanism for these episodes is one of ion exchange in the catchment soils following precipitation inputs laden with sea-salts. The investigation indicates the potential importance of sea-salts in streamwater acidification within the British context. The data provide insights into the mechanisms of acidification from precipitation input to ftreamwater output.

The nature of soil-water interactions is discussed in the context of both soil formation and drainage water chemistry. The interacting factors regulating drainage water chemistry are then briefly considered, including soil type and parent material, soil atmosphere CO2 concentration, hydrological pathways, soluble salts, topography, climate and biotic effects. Based upon these factors, some sites in NE Scotland thought to be highly susceptible to water acidification are examined, and the low pH of their waters is confirmed. The acidity trends of two superficially similar streams apparently less at risk are compared, and the differences explained in terms of sub-surface soil characteristics. The possible impacts of both afforestation and of acidifying pollutants on water pH are considered briefly where appropriate.