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ART. 256 - On the Weight of Hydrogen desiccated by Liquid Air

Published online by Cambridge University Press:  05 July 2011

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Summary

In recent experiments by myself and by others upon the density of hydrogen, the gas has always been dried by means of phosphoric anhydride; and a doubt may remain whether on the one hand the removal of aqueous vapour is sufficiently complete, and on the other whether some new impurity may not be introduced. I thought that it would be interesting to weigh hydrogen dried in an entirely different manner, and this I have recently been able to effect with the aid of liquid air, acting as a cooling agent, supplied by the kindness of Professor Dewar from the Royal Institution. The operations of filling and weighing were carried out in the country as hitherto. I ought, perhaps, to explain that the object was not so much to make a new determination of the highest possible accuracy, as to test whether any serious error could be involved in the use of phosphoric anhydride, such as might explain the departure of the ratio of densities of oxygen and hydrogen from that of 16 : 1. I may say at once that the result was negative.

Each supply consisted of about 6 litres of the liquid, contained in two large vacuum-jacketed vessels of Professor Dewar's design, and it sufficed for two fillings with hydrogen at an interval of two days. The intermediate day was devoted to a weighing of the globe empty.

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Publisher: Cambridge University Press
Print publication year: 2009
First published in: 1903

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