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2 - Governing Equations of Chemical Kinetics and Specific Features of Their Solution

from Part I - Basic Components of Chemical Nonequilibrium Models

Published online by Cambridge University Press:  16 August 2019

V. I. Naoumov ,
V. G. Krioukov ,
A. L. Abdullin  and
A. V. Demin
V. I. Naoumov
Affiliation:
Central Connecticut State University
V. G. Krioukov
Affiliation:
Kazan National Research Technical University, Russian Federation
A. L. Abdullin
Affiliation:
The Academy of Science of the Republic of Tatarstan, Russian Federation
A. V. Demin
Affiliation:
Kazan State Power Engineering University, Russian Federation
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Summary

Equations of gas-phase chemical kinetics (1.85) (see Section 1.3) are valid for a constant volume (V = const) BR, while occurring a reversible chemical reactions. However, in the general case, it is desirable to allow for volume variation (V = var) in the reactor R, or in an assumed reactor of the system of reactors (SR), as well as in occurrences of irreversible reactions herein, feed and discharge of substances and surface reactions [5]. Such reactions reflect the change in gas mass and its composition in the reactor due to a number of processes (for example, evaporation, condensation, combustion of metals and coal, absorption, etc.).

Type
Chapter
Information
Chemical Kinetics in Combustion and Reactive Flows
Modeling Tools and Applications
 , pp. 41 - 94
Publisher: Cambridge University Press
Print publication year: 2019

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