The diffusive exchange of dissolved material between fluid flowing in a fracture and the enclosing wallrocks (rock matrix diffusion) has been proposed as a mechanism by which radionuclides derived from a radioactive waste repository may be removed from groundwater and incorporated into the geosphere. To test the effectiveness of diffusive exchange in igneous and metamorphic rocks, we have carried out an investigation of veins formed at low temperatures (<100°C), comparing the oxygen isotopic composition of vein calcite with that of secondary calcite in the wallrocks. Two examples of veins from the Borrowdale Volcanic Group, Cumbria, and one from the Mountsorrel Granodiorite, Leicestershire, UK, have remarkably similar vein calcite compositions, ca. +20‰(SMOW) or greater, substantially heavier than the probable compositions of the host rocks, and these vein calcite compositions are inferred to reflect the infiltrating fluid and the temperature of vein formation. Calcites from the wallrocks are similar to those in veins, with little evidence for exchange with the wallrocks. The results support existing models for this type of vein which suggest low-temperature growth from formation brines originally linked to Permian or Triassic evaporites. The results are consistent with flow through fractures being attenuated through a damage zone adjacent to the fracture and provide no evidence of diffusional exchange with pore waters from wallrocks.

The extent to which persistent, rather than transient, fissures (wide planar voids) can exist along upper crustal faults is important in assessing fault permeability to mineral and hydrocarbon-bearing fluids. Variscan (late Carboniferous) faults cutting Dinantian (Lower Carboniferous) limestones on the Gower peninsula, South Wales, host clear evidence for fissures up to several metres wide. Evidence includes dendritic hematite growth and elongate calcite growth into open voids, spar ball and cockade breccia formation, laminated sediment infill and void-collapse breccias. Detailed mapping reveals cross-cutting geometries and brecciation of earlier fissure fills, showing that fissures were formed during, rather than after, active faulting. Fissures therefore probably formed by geometric mismatch between displaced fault walls, rather than by solution widening along inactive faults.

A complication is an event or occurrence that is associated with a disease or a healthcare intervention, is a departure from the desired course of events, and may cause, or be associated with, suboptimal outcome. A complication does not necessarily represent a breech in the standard of care that constitutes medical negligence or medical malpractice. An operative or procedural complication is any complication, regardless of cause, occurring (1) within 30 days after surgery or intervention in or out of the hospital, or (2) after 30 days during the same hospitalization subsequent to the operation or intervention. Operative and procedural complications include both intraoperative/intraprocedural complications and postoperative/postprocedural complications in this time interval.

The MultiSocietal Database Committee for Pediatric and Congenital Heart Disease has set forth a comprehensive list of complications associated with the treatment of patients with congenital cardiac disease, related to cardiac, pulmonary, renal, haematological, infectious, neurological, gastrointestinal, and endocrinal systems, as well as those related to the management of anaesthesia and perfusion, and the transplantation of thoracic organs. The objective of this manuscript is to examine the definitions of operative morbidity as they relate specifically to a collection of loosely related topics that include the following groups of complications: 1) Complications of the Integument, 2) Complications of the Vascular System, 3) Complications of the Vascular-Line(s), 4) Complications of Wounds. These specific definitions and terms will be used to track morbidity associated with surgical and transcatheter interventions and other forms of therapy in a common language across many separate databases.

As surgical survival in children with congenital cardiac disease has improved in recent years, focus has necessarily shifted to reducing the morbidity of congenital cardiac malformations and their treatment. A comprehensive list of complications is presented. This list is a component of a systems-based compendium of complications that will standardize terminology and thereby allow the study and quantification of morbidity in patients with congenital cardiac malformations. Clinicians caring for patients with congenital cardiac disease will be able to use this list for databases, initiatives to improve quality, reporting of complications, and comparing strategies of treatment.

Graphite bodies of economic importance occur in the Eastern Ghats migmatite complex of Orissa, India, which consists of sillimanite-rich gneiss (khondalite), calc-silicate granulite, basic (pyroxene) granulite and acidic gneiss palaeosomes and a variety of quartzofeldspathic neosomes and pegmatite veins. There is more graphite in migmatised khondalite and calc-silicate granulite than in their unmigmatised counterparts and it is common at pegmatite-country rock margins. Lodes of graphite are structurally controlled by fold hinge zones, necks of boudins and along the dominant foliation in rocks that show the effects of polyphase deformation. Faults, fractures and joints also act as structural controls. The richest lodes are located where there is the coincidence of several lithological and structural features.

The graphite occurs in graphite-rich schists and gneisses, as veins and as disseminated flakes along grain boundaries and in microfractures and cleavages. It is present in all rock types except pegmatites emplaced after the D4 deformational phase, and is localised in structures developed during the D1, D2, D3 and D4 phases. Most of the bodies of graphite are lenticular and show pinch and swell characters. Fourteen textural and microstructural habits have been recognised and are described with many of the features of fabric, such as intergrowths, inclusions and kinks being particularly well shown under reflected light.

Methanation of carbonate minerals is considered the most likely initial stage in the formation of the carbon with subsequent pyrolysis of the methane being the process of graphitisation. While the possibility of the carbon being either of sedimentary derivation orfrom igneous-derived CO2 cannot be ruled out, there is no convincing evidence for such sources. Remobilisation of graphite following its formation by pyrolysis of methane in structurally controlled low pressure zones is the dominant mechanism of concentration. Thefabric features point to the graphite having moved as a solid phase along open spaces inthe gangue minerals while still maintaining its crystallinity, and having been deformed in the process. The effects of remobilisation apparently have obliterated evidence relating to other methods of concentration.