Lead, zinc and arsenic mobilization/attenuation processes during interactions between smelter slag and water show differences depending on the origin of the slag. The studied samples, waste from ore and car-battery processing, were submitted to long-term (365 days) batch leaching at two different initial pH values. The leachate analyses were input to the EQ3NR speciation-solubility code to speciate the solutions and determine the degree of saturation with respect to different phases, and a mineralogical investigation was made of the newly formed phases. An ‘oxidizing’ scenario can be proposed for slag waste disposal, considering that cerussite (PbCO3) at pH >6 becomes a major solubility-controlling phase for Pb, and newly formed hydrous ferric oxides (HFO – common secondary phases under oxidizing conditions) efficiently adsorb As. No efficient scavenging mechanism was found for Zn, which was progressively leached from the slag and in particular from the ore-processing slag. Quenched glass-rich slag from old car-battery processing was found to release significant amounts of Pb, especially in acidic environments. Neither slag would therefore be suitable for recycling for civil engineering purposes. Conversely, extremely low releases of Pb, Zn and As were observed for recent car-battery processing slag, which could therefore be considered for road construction.

Lake-ice properties at Lake Abashiri, Hokkaido, Japan, were examined using field observations and a 1-D thermodynamic model to clarify formation processes at mid-latitudes subject to significant snowfall as well as moderate air temperature. At all lake sites examined, the ice comprised two distinct layers: a snow ice (SI) layer on top and a congelation ice (CI) layer below. The SI layer occupied as much as 29–73% of the total ice thickness, a much greater fraction than that reported for lakes at Arctic high latitudes. In the model, the CI growth rate was estimated using the traditional heat budget method, while the SI growth rate was calculated assuming the excessive snowfall from the isostatic balance is converted to SI by a snow compression rate (β) with the surface melting rate added when the surface heat budget becomes positive. By tuning the value of β to the observational results of SI thickness, the model outcome successfully reproduced the observational thicknesses of CI and SI, and the break-up date of the lake. Essentially, the model findings show how snow and its formation into SI reduce, by about half, the seasonal variability of total ice thickness.

Understanding the controls on the evolution of natural feldspars is greatly assisted by coupling experimental determinations of feldspar/melt equilibria with thermodynamic modelling and the calculation of crystallisation paths. Such a combined approach permits the evaluation of the influence of intensive and extensive variables on feldspar compositions. Feldspar compositional paths are influenced only to a minor degree by pressure. The presence of H2O or other melt component incompatible in feldspar has a more major effect, not only in increasing the temperature interval over which feldspar crystallises, but also in decreasing the amount of Ab enrichment of the feldspar which occurs during crystallisation. The amount and behaviour of H2O in the magma has a pronounced influence on feldspar compositions when two feldspars are stable. Under conditions of high bulk H2O content or constant activity of H2O, plagioclase and alkali feldspar compositions evolve by increasing Ab content similar to the behaviour manifested in the simple binary systems. If the bulk H2O content is low, however, and the H2O content increases during crystallisation, plagioclase evolves by increasing Ab content until alkali feldspar is stabilised. From that point on, plagioclase compositions change mainly by decreasing Or content, while alkali feldspar evolves mainly by increasing Or content.