The Magellanic Stream (MS), a tail of diffuse gas formed from tidal and ram pressure interactions between the Small and Large Magellanic Clouds (SMC and LMC) and the Halo of the Milky Way, is primarily composed of neutral atomic hydrogen (HI). The deficiency of dust and the diffuse nature of the present gas make molecular formation rare and difficult, but if present, could lead to regions potentially suitable for star formation, thereby allowing us to probe conditions of star formation similar to those at high redshifts. We search for $\text{HCO}^{+}$, HCN, HNC, and C$_2$H using the highest sensitivity observations of molecular absorption data from the Atacama Large Millimeter Array (ALMA) to trace these regions, comparing with HI archival data from the Galactic Arecibo L-Band Feed Array (GALFA) HI Survey and the Galactic All Sky Survey (GASS) to compare these environments in the MS to the HI column density threshold for molecular formation in the Milky Way. We also compare the line of sight locations with confirmed locations of stars, molecular hydrogen, and OI detections, though at higher sensitivities than the observations presented here.

We find no detections to a 3$\sigma$ significance, despite four sightlines having column densities surpassing the threshold for molecular formation in the diffuse regions of the Milky Way. Here we present our calculations for the upper limits of the column densities of each of these molecular absorption lines, ranging from $3 \times 10^{10}$ to $1 \times 10^{13}$ cm$^{-2}$. The non-detection of $\text{HCO}^{+}$ suggests that at least one of the following is true: (i) $X_{\text{HCO}^{+}{}, \mathrm{MS}}$ is significantly lower than the Milky Way value; (ii) that the widespread diffuse molecular gas observed by Rybarczyk (2022b, ApJ, 928, 79) in the Milky Way’s diffuse interstellar medium (ISM) does not have a direct analogue in the MS; (iii) the HI-to-$\text{H}_{2}$ transition occurs in the MS at a higher surface density in the MS than in the LMC or SMC; or (iv) molecular gas exists in the MS, but only in small, dense clumps.

We investigated the kinematics and dynamics of gas structures on galaxy-cloud scales in two spiral galaxies NGC5236 (M83) and NGC4321 (M100) using CO (2$-$1) line. We utilised the FILFINDER algorithm on integrated intensity maps for the identification of filaments in two galaxies. Clear fluctuations in velocity and density were observed along these filaments, enabling the fitting of velocity gradients around intensity peaks. The variations in velocity gradient across different scales suggest a gradual and consistent increase in velocity gradient from large to small scales, indicative of gravitational collapse, something also revealed by the correlation between velocity dispersion and column density of gas structures. Gas structures at different scales in the galaxy may be organised into hierarchical systems through gravitational coupling. All the features of gas kinematics on galaxy-cloud scale are very similar to that on cloud-clump and clump-core scales studied in previous works. Thus, the interstellar medium from galaxy to dense core scales presents multi-scale/hierarchical hub-filament structures. Like dense core as the hub in clump, clump as the hub in molecular cloud, now we verify that cloud or cloud complex can be the hub in spiral galaxies. Although the scaling relations and the measured velocity gradients support the gravitational collapse of gas structures on galaxy-cloud scales, the collapse is much slower than a pure free-fall gravitational collapse.