The cosmic origin of fluorine is still under debate. Asymptotic giant branch (AGB) stars are among the few suggested candidates to efficiently synthesis F in our Galaxy, however their relative contribution is not clear. In this paper, we briefly review the theoretical studies from stellar yield models of the F synthesis and chemical equilibrium models of the F-containing molecules in the outflow around AGB stars. Previous detections of the F-bearing species towards AGB and post-AGB stars are also highlighted. We suggest that high-resolution ALMA observations of the AlF, one of the two main carriers of F in the outflow of AGB stars, can provide a reliable tracer of the F-budget in AGB stars. This will be helpful to quantify the role of AGB stars in the Galactic F budget.