We review the effective temperature scale of hot (≤ 10 kK) stars, including results from direct, continuum and ionization equilibrium techniques. We discuss the impact of recent developments in theoretical model atmospheres for OB subdwarfs, dwarfs and supergiants, white dwarfs and Wolf Rayet stars and present a revised Teff scale for OB stars. Direct techniques coupled with Kurucz model atmospheres allow Strömgren photometry to be used as a sensitive Teff indicator for normal stars with Teff ≥ 25 kK. Reliable Teff determinations for hotter, low surface gravity and H-deficient stars require sophisticated ionization equilibrium techniques, generally considering non-LTE and line-blanketing effects.