Khovanov–Lauda–Rouquier (KLR) algebras of finite Lie type come with families of standard modules, which under the Khovanov–Lauda–Rouquier categorification correspond to PBW bases of the positive part of the corresponding quantized enveloping algebra. We show that there are no non-zero homomorphisms between distinct standard modules and that all non-zero endomorphisms of a standard module are injective. We present applications to the extensions between standard modules and modular representation theory of KLR algebras.