The binary exchange of cations on clays and soils is generally regarded as a thermodynamically reversible process. The literature on soil chemistry and geochemistry, however, abounds with reports on cation exchange reactions that appear to have only limited reversibility, i.e., that exhibit hysteresis. A satisfactory explanation of this phenomenon is still lacking, even though a number of mechanisms have been advocated, e.g., charge or site heterogeneity at the surface, differential hydration of cations, dehydration of the exchanger, crystalline swelling hysteresis, and inaccessibility of sites caused by domain or quasi-crystal formation. In the present article, the relevant literature is reviewed and analyzed critically. On the basis of available evidence, it is shown that exchangeable cations can be classified into three groups, defined in such a way that hysteresis has, in the literature, generally not been observed when exchange reactions involved cations belonging to the same group, but has often been found when the reactions involved cations from different groups. Furthermore, it is argued that none of the five mechanisms mentioned can, in and of itself, account fully for the observed exchange hysteresis. A conceptual model is proposed that combines elements of these five mechanisms and is able to describe, at least qualitatively, the effects of factors such as clay type, electrolyte concentration, and extent of dehydration.

Due to the high brittleness, cracks, holes, and other defects that are easily generated in quasi-crystal structures can affect safe applications in serious cases. For guided wave non-destructive testing, the propagation of Lamb and SH waves in functionally graded one-dimensional hexagonal quasi-crystal plates are investigated. Governing equations of wave motion in the context of Bak’s model are deduced and solved by the Legendre orthogonal polynomial method. Dispersion curves, phonon and phason displacement, and stress distributions are illustrated. The convergence of the present method applied to functionally graded quasi-crystal plates is verified. Moreover, the influences of the phonon-phason coupling effect and graded fields on wave characteristics are analyzed. Some new results are obtained: angular frequencies of phason modes always decrease as phonon-phason coupling coefficients, Ri, increase; and phonon and phason displacements of Lamb and SH waves at high frequencies are mainly distributed in the region that contains more quasi-crystal material with a smaller elasticity modulus and less rigidity. The obtained results establish the theoretical foundation of guided wave non-destructive testing for functionally graded quasi-crystal plates.

Metal-matrix composites are produced from Al powder and 30 vol% of icosahedral Al–Cu–Fe quasi-crystalline particles using a hot isostatic pressing technique. It is demonstrated that the initial icosahedral phase is transformed into the ω-Al70Cu20Fe10 tetragonal phase during the hot isostatic pressing (HIP) process. The mechanical properties of the composite were evaluated over the temperature range 293 to 773 K by performing compression tests at constant strain rate. The temperature dependence of the yield stress gives evidence of two temperature regimes with a transition temperature at approximately 423 K. Strain-rate sensitivity measurements support the change in rate-controlling deformation mechanisms at this temperature. It is proposed that cross-slip and/or climb mechanism control plastic flow. Finally, it is suggested that the phase transformation of the particle contributes positively to the improvement of the mechanical properties.