Glyphosate toxicity to wheat was antagonized more by calcium chloride than sodium bicarbonate. Mixtures of the salts at greater than 100 mg L−1 sodium bicarbonate and 200 mg L−1 calcium chloride were additive in antagonism of glyphosate in the greenhouse experiments. Surfactant and oil adjuvants did not overcome sodium bicarbonate or calcium chloride antagonism of glyphosate. Oil adjuvants were generally antagonistic to glyphosate. An equation is presented that determines the amount of diammonium sulfate required to overcome glyphosate antagonism based upon the sodium, potassium, calcium, and magnesium cations in the spray carrier.

Experiments were conducted in the greenhouse to determine nicosulfuron activity on large crabgrass as influenced by surfactant, ammonium salt adjuvants, and various calcium, sodium, and magnesium salts in the spray carrier. Nicosulfuron activity varied with surfactant. Ammonium salt adjuvants at 0.2 M (ammonia) and sodium, calcium, or magnesium salts at 0.02 M (cation) increased or decreased nicosulfuron activity dependent on the specific salt and surfactant. Spray carrier surface tension or pH of the spray solution did not relate to nicosulfuron activity. The specific ammonium component influenced nicosulfuron activity differently depending on the surfactant. Increases in ammonium nitrate concentration decreased, nicosulfuron activity with Pluronic® P85 surfactant and increased activity with X-77® surfactant. The response to ammonium nitrate was less pronounced at high surfactant concentrations. Sodium bicarbonate antagonism of nicosulfuron activity was overcome by ammonium sulfate and 28% aqueous nitrogen fertilizer in the presence of several oil and surfactant adjuvants. The results indicate the importance of surfactant selection for use with nicosulfuron when applied with nitrogen salts.

The effects of herbicide concentration, adjuvants, and temperature on the phytotoxicity of CGA-82725 {2-propynyl 2-[4-[3,5-dichloro-2-pyridinyl)oxy] phenoxy] propionate}, RO 13-8895 {acetone-O-[D-2-[p-(α,α,α-trifluoro-p-tolyl)-oxy] phenoxy] propionyl] oxime}, and BAS 9052 OH {2-[1-(ethoxyimino)-butyl]-5-[2-(ethylthio)propyl]-3-hydroxy-2-cyclohexene-1-one} to large crabgrass [Digitaria sanguinalis (L.) Scop. # DIGSA] were evaluated. The addition of adjuvants increased the toxicity of BAS 9052 OH at herbicide rates below 0.14 kg ai/ha, whereas the adjuvants had little effect on the activity of CGA-82725 or RO 13-8895. There were no differences among the adjuvants in enhancing grass control with any of the herbicides. Control of large crabgrass with CGA-82725 or BAS 9052 OH was not affected by temperature at the time of spraying; RO 13-8895 was slightly more toxic at 16 C than at 32 C. Soybean [Glycine max (L.) Merr.] had good tolerance to the three herbicides at rates 3 to 10 times those recommended; no differences in tolerance were observed among seven soybean cultivars. Stage of growth and the addition of an emulsifiable oil adjuvant did not affect soybean tolerance to BAS 9052 OH.