Consecutive annual applications of alachlor [2-chloro-N-(2,6-diethylphenyl)-N-(methoxymethyl)acetamide] and metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl)acetamide] were made to continuous no-till corn (Zea mays L. ‘Pioneer 3184’ in 1982 and 1983, ‘Pioneer 3744’ in 1984, and ‘Pioneer 3378’ in 1985 to 1987). In a 5-yr study, control of the dominant annual grass species, large crabgrass [Digitaria sanguinalis (L.) Scop. # DIGSA], by alachlor declined to less than 50% by the fifth year. Control of large crabgrass by metolachlor remained greater than 80% throughout the study but metolachlor allowed the establishment of a greater fall panicum (Panicum dichotomiflorum Michx. # PANDI) population in this and an additional 3-yr study than in chloroacetamide-free checks. In the 3-yr study in which giant foxtail (Setaria faberi Herrm. # SETFA) was dominant, annual applications of metolachlor and a microencapsulated formulation of alachlor provided better control in the second year than the emulsifiable concentrate formulation of alachlor, but formulation differences diminished in the third year.

The activity of emulsifiable concentrate (EC) formulation of pendimethalin was studied using a petri dish bioassay based on root response of corn, oat, sorghum, and sugar beet grown in soil. Furthermore, the oat bioassay was used to determine the activity of EC, microencapsulated (ME), and water-dispersible granule (WDG) formulations of pendimethalin. Also, field persistence in soil of these pendimethalin formulations was studied with petri dish and pot bioassays, based on root response of oat and sugar beet. All bioassays indicated that activity of all pendimethalin formulations was increased with increasing herbicide concentration. In silty clay loam soil, oat and sugar beet exhibited the highest sensitivity to EC-pendimethalin concentrations and corn the lowest; sorghum showed intermediate herbicide sensitivity. EC of pendimethalin showed the highest activity on oat and ME pendimethalin the lowest; WDG-pendimethalin showed similar activity to that of ME pendimethalin. Field persistence was significantly increased with increasing rate of application, but it was slightly increased by the ME formulation.