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metal sorption

Cambridge University Press (1)

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36 - Contamination and Remediation
from PART III - APPLIED REACTION MODELING
Craig M. Bethke, University of Illinois, Urbana-Champaign
Book:

Geochemical and Biogeochemical Reaction Modeling

Published online:

09 December 2021

Print publication:

06 January 2022, pp 431-438
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Summary

We construct in this chapter reactive transport models of the mobility of heavy metals in an aquifer containing a complexing surface. The modeling shows that surface complexation can play a controlling role in the fate and transport of heavy metal contamination in the environment. Surface complexation causes not only retardation, as might be expected from simple sorption theory, but a pronounced tailing that hinders remediation by pump-and-treat methods.