Cryogenic brines are under-studied, despite the fact that they may contain information about past ice-sheet behavior. Cryogenic brines form through cryoconcentration of seawater, although the specific setting and mechanism of formation have been debated. Previous conceptual models of brine formation require seawater isolation from the ocean in a closed basin experiencing freezing. We propose instead that they may form in pore spaces of marine sediments subjected to repeat cycles of ice-sheet advance and retreat. During periods of basal freezing, cryoconcentration produces hypersaline brines which experience downward flow driven by unstable density stratification. Our advection-diffusion model of porewater chemistry evolution successfully recreates the porewater chemistry of two deep Antarctic cores containing cryogenic brines (AND-1B and AND-2A), suggesting that cryogenic brines can be formed through the repeated isolation and cryoconcentration of marine waters within subglacial sediment pore spaces of modern and past ice sheets.

Over the last two decades, anomalous warming events have been observed in coastal Antarctic regions. While these events have been documented in the Ross Sea sector, the Antarctic interior is believed to have been buffered from warming. In this work, we present data from lakes located near Mt. Heekin and Thanksgiving Valley (~85° S) along the Shackleton Glacier, which are believed to be the southern-most Antarctic dry valley lakes. In 2018, the lakes were characterized, repeat satellite images were examined, and lake water chemistry was measured. Our analysis shows that lake areas recently increased, and the water-soluble ion chemistry indicates a flushing of salts from periglacial soils, likely from increased glacial melt as illustrated by water isotope data. Our results show that high southern latitude ice-free areas have likely been affected by warm pulses over the past 60 years and these pulses may be quasi-synchronous throughout the Transantarctic Mountains.

Predicting the isotopic modification of ice by melting processes is important for improving the accuracy in paleoclimate reconstruction. To this end, we present results from cold room laboratory observations of changes in the isotopic ratio (D/H and 18O/16O) of ice cubes by isotopic exchange between liquid water and ice in nearly isothermal conditions. A 1-D model was fit to the isotopic results by adjusting the values of two parameters, the isotopic exchange rate constant (kr) and the fraction of ice participating in the exchange (f). We found that the rate constant for hydrogen isotopic exchange between liquid water and ice may be greater (up to 40%) than that for the oxygen isotopic exchange. The range of the rate constant obtained from four melt experiments is from 0.21 to 0.82 h–1. The model results also suggest that f decreases with the increasing wetness of the ice. This is because with increasing water saturation in ice, water may be present only in the small pores or some of the water that was exchanged with ice may be bypassed, decreasing the effective surface area over which the isotopic exchange can occur. The relationship between the two water isotopes (δ18O vs δD) was observed and modeled and the slope was <8, which is significantly different from the slope of the meteoric waterline. We note that these slopes were obtained without considering the sublimation process.

Cryoconite holes play a significant role in the nutrient cycling on glaciers and can be regarded as a storehouse of nutrients that are generated through microbial and photochemical activities. In this work, the chemical characteristics of hydrologically connected and isolated cryoconite holes from three geographically distinct regions of coastal Antarctica, namely Larsemann Hills, Amery Ice Shelf and central Dronning Maud Land were studied. Major ions (Na+, K+, Mg2+, Ca2+, Cl−, SO42− and NO3−) and total organic carbon in the hydrologically isolated, closed cryoconite holes showed significantly higher enrichment (6–26 times and 9 times, respectively) over the conservative tracer ion Cl− possibly due to sediment dissolution and microbial synthesis during isolation period. In contrast, depletion of major ions and organic carbon were observed in the open, hydrologically connected holes due to their discharge from the cryoconite holes through interconnected streams. This study suggests that the contribution of cryoconite holes to the nutrient and microbial transport to downstream environments may vary with the extent of hydrological connectivity by virtue of the fact that nutrients and organic carbon which accumulate in the isolated cryoconite holes during isolation could get washed to downstream environments in the event that they get connected through surface or subsurface melt channels.

Jakobshavn Isbræ, which terminates in Ilulissat Icefjord, has undergone rapid retreat and is currently the largest contributor to ice-sheet mass loss among Greenland's marine terminating glaciers. Accelerating mass loss is increasing fresh water discharge to the ocean, which can feed back on ice melt, impact marine ecosystems and potentially modify regional and larger scale ocean circulation. Here we present hydrographic observations, including inert geochemical tracers, that allow the first quantitative description of the glacially-modified waters exported from the Jakobshavn/Icefjord system. Observations within the fjord suggest a deep-reaching overturning cell driven by glacial buoyancy forcing. Modified waters containing submarine meltwater (up to 2.5 ± 0.12%), subglacial discharge (up to 6 ± 0.37%) and large portions of entrained ocean waters are seen to exit the fjord and flow north. The exported meltwaters form a buoyant coastal gravity current reaching to 100 m depth and extending 10 km offshore.

The subglacial chemical weathering environment is largely controlled by low temperatures and the presence of freshly comminuted minerals with a high surface area. These characteristics are believed to promote dissolution processes that give rise to low silica and high Ca2+ fluxes emanating from glacierized basins. We test an alternative hypothesis, that mineral precipitation reactions in the subglacial environment play an equally important role in controlling the water chemistry in glacierized basins. We analyze borehole and proglacial water chemistry from a subarctic polythermal glacier, complemented by mineral XRD analysis of suspended sediment, till and bedrock samples. In conjunction with a thermodynamic analysis of the water and mineral chemistry, we use reaction-path modelling to study the chemical enrichment of water through the glacier system. We find that the high pH of the subglacial environment is conducive to secondary mineral precipitation, and that it is not possible to balance the water chemistry using dissolution reactions alone. We show that low silica can be explained by standard weathering reactions without having to invoke mineral-leaching reactions. Our results suggest that subglacial weathering intensity may be significantly underestimated if the production of secondary minerals is not considered.

Melt layers are clear indicators of extreme summer warmth on polar ice caps. The visual identification of refrozen meltwater as clear bubble-free layers cannot be used to study some past warm periods, because, in deeper ice, bubbles are lost to clathrate formation. We present here a reliable method to detect melt events, based on the analysis of Kr/Ar and Xe/Ar ratios in ice cores, and apply it to the detection of melt in clathrate ice from the Eemian at NEEM, Greenland. Additionally, melt layers in ice cores can compromise the integrity of the gas record by dissolving soluble gases, or by altering gas transport in the firn, which affects the gas chronology. We find that the easily visible 1 mm thick bubble-free layers in the WAIS Divide ice core do not contain sufficient melt to alter the gas composition in the core, and do not cause artifacts or discontinuities in the gas chronology. The presence of these layers during winter, and the absence of anomalies in soluble gases, suggests that these layers can be formed by processes other than refreezing of meltwater. Consequently, the absence of bubbles in thin crusts is not in itself proof of a melt event.

Virkisjökull is a rapidly retreating outlet glacier draining the western flanks of Öræfajökull in SE Iceland. Since 2011 there have been continuous measurements of flow in the proglacial meltwater channel and regular campaigns to sample stable isotopes δ2H and δ18O from the river, ice, moraine springs and groundwater. The stable isotopes provide reliable end members for glacial ice and shallow groundwater. Analysis of data from 2011 to 2014 indicates that although ice and snowmelt dominate summer riverflow (mean 5.3–7.9 m3 s−1), significant flow is also observed in winter (mean 1.6–2.4 m3 s−1) due primarily to ongoing glacier icemelt. The stable isotope data demonstrate that the influence of groundwater discharge from moraines and the sandur aquifer increases during winter and forms a small (15–20%) consistent source of baseflow to the river. The similarity of hydrological response across seasons reflects a highly efficient glacial drainage system, which makes use of a series of permanent englacial channels within active and buried ice throughout the year. The study has shown that the development of an efficient year round drainage network within the lower part of the glacier has been coincident with the stagnation and subsequent rapid retreat of the glacier.

Glacier naledi are extrusive ice masses that appear in front of glaciers as a consequence of refreezing of meltwater seepage during the accumulation season. These structures provide a unique opportunity to understand subglacial drainage activity during the accumulation season; however, only few detailed studies have previously focused on their characteristics. Here, we investigated glacier-derived naled assemblages in the proglacial zone of the polythermal glacier Werenskioldbreen (27.4 km2) in SW Svalbard. We determined the spatial distribution of naledi using ground penetrating radar surveys. The main subglacial drainage pattern was related to a channel under the medial moraine, and three sources are linked to a distributed subglacial drainage network. The relation between atmospherically-corrected (Ca2+ + Mg2+) and (SO4 2−) in sub-naled waters was closely related to sulphide oxidation coupled with carbonate dissolution (r = 0.99; slope = 1.6). This is consistent with the local lithology, which is dominated by schist containing carbonates. We also found high carbonate saturation indices in pale white ice layers within the naled. We conclude that sulphide oxidation coupled with carbonate dissolution is the dominant chemical weathering process in the subglacial drainage system of Werenskioldbreen during the accumulation season.

Water stored as ice and snow at high elevations is a resource that plays an important role in the hydrologic cycle, particularly in the timing and volume of downstream discharge. Here we use geochemical and isotopic values of water samples to evaluate relative contributions of melting glacier ice and groundwater to discharge in Bhutan. River water samples were collected between 3100 and 4500 m in the Chamkar Chhu (river) watershed of central Bhutan's Himalaya. Glacier ice and snow were sampled in the ablation zone of Thanagang glacier. Groundwater was parameterized from spring water at elevations of 3100 and 3600 m. Synoptic sampling was carried out in separate expeditions in July, August and late September 2014, to characterize monsoon and post-monsoon conditions. Results from a two-component hydrologic mixing model using isotopic and geochemical (sulphate) values show that the glacier outflow contributions decrease from ∼76% at 4500 m to 31% at 3100 m. A four-component hydrologic mixing model using end-member mixing analysis shows glacier ice melt increasing as a proportion of discharge over the 3 month sampling period, and consistently decreasing with distance downstream of Thanagang glacier terminus. These results indicate that isotopic and geochemical tracers can provide a quantitative evaluation of the source water contributions to streamflow in Bhutan.

Understanding the hydrology of glacierized catchments is an important step in assessing the vulnerability of water resources to a changing climate. While there have been increased efforts recently to understand the dynamics of Asia's cryosphere, glacier melt dynamics and hydrograph separation of river discharge are open questions. A multi-year, multi-seasonal dataset of water chemistry from the Langtang Valley, Nepal, is used to explore water sources and flow paths that contribute to Langtang River discharge. Differences in hydrochemistry of samples from debris-free Khimsung Glacier and debris-covered Lirung Glacier demonstrate the effect of debris cover on glacier outflow. Additional data show seasonal transitions in the composition of Langtang River discharge. End-member mixing analysis (EMMA) using geochemical and isotopic tracers suggests that reacted meltwater contributes the majority of flow during most of the year, with the exception of the summer when unreacted meltwater and precipitation dominate streamflow. We hypothesize our dataset is missing characteristic monsoon water and utilize a Late May river sample as a proxy for precipitation-influenced groundwater in the EMMA. Results offer insight into the plausibility of flow sources and pathways in the basin.