We are concerned with a 2D time harmonic wave propagationproblem in a medium including a thin slot whose thickness εis small with respect to the wavelength. In a previous article, we derivedformally an asymptotic expansion of the solution with respect to εusing the method of matched asymptotic expansions. We also proved theexistence and uniqueness of the terms of the asymptotics. In this paper,we complete the mathematical justification of our work by deriving optimal error estimates between the exact solutions and truncated expansions at any order.