Johninnesite, ideally Na2Mg4Mn12As5+2 Si12043(OH)6,, is triclinic, P1 or P1̄, with a = 10.44(2), b = 11.064(6), c = 9.62(1) Å, α = 107.43(7), β = 82.7(1), γ = 111.6(1)°, V = 894(2) Å3, and Z = 1. It occurs as yellow-brown fibrous aggregates, associated with rhodonite, kentrolite, and richterite, from the Kombat Mine in Namibia. Johninnesite has cleavages on {100} and {010}, density of 3.48 (meas.), 3.51 (calc.) g/cm3. It is biaxial negative, with 2Vx = 41.9°, α = 1.6742(4), β = 1.6968(3), γ = 1.6999(3); dispersion r > υ, distinct.