This paperpresents the measurement procedure as well as the calculations and theoretical background for the estimation of particle sizes with the help of a dual-frequency measurement setup. For the measurement, two fully integrated radar sensors are implemented which offer advantages over typically used technologies at high frequencies. The first sensor has a constant transmitting frequency of 90 GHz while the second sensor offers a possibility to vary the transmitting frequency over the entire D-band with frequencies between 110 and 180 GHz. With these frequencies, different sizes can be determined. The presented approach makes use of the different transitions between the linear increasing Rayleigh scattering regime and the Mie regime. With a fitting indoor measurement setup that resembles an industrial duct, the approach is verified for spheroid glass particles with a diameter of 0.875 mm. The results show a slight deviation from the expected value of particle sizes overall.