The optimal stopping value of random variables X1,…,Xn depends on the joint distribution function of the random variables and hence on their marginals as well as on their dependence structure. The maximal and minimal values of the optimal stopping problem is determined within the class of all joint distributions with fixed marginals F1,…,Fn. They correspond to some sort of strong negative or positive dependence of the random variables. Any value inbetween these two extremes is attained for some dependence structures. The determination of the minimal value is based on some new ordering results for probability measures, in particular on lattice properties of stochastic orderings. We also identify properties of dependence structures leading to the minimal optimal stopping value. In the proofs we need an extension of Strassen's theorem on representation of the convex order which reveals that convex ordered distributions can be coupled by a two-step martingale (X,Y) with the additional property that Y is stochastically increasing in X.