We constructed a laser ablation (LA) system using a diode laser for the accelerator mass spectrometry radiocarbon (AMS 14C) measurement of organic materials. The system could extract adequate CO2 to analyze small masses (0.1 mg C) at a resolution of 250 µm by a 5.5 W diode laser. The LA system was assessed using standard materials (IAEA-C1, IAEA-C2, IAEA-C3, IAEA-C6, and Ox II) and applied to natural tree ring samples. For the LA sampling of organic samples, which generally results in incomplete combustion, tungsten (VI) oxide was used as an oxidant to achieve complete burning. The results of the measurement of standard materials showed a low 14C background of F14C 0.0085 ± 0.0005 and reasonable reproduction of 14C values. Finally, we applied this system to a single-year analysis of tree-ringed spruce timber in Alaska. It was observed to have a detectable background for the 14C bomb peak.

Tailored diode laser single emitters with long (6 mm) resonators and wide (1.2 mm) emission apertures that operate with 940 nm emission wavelength were assembled in novel edge-cooled vertically stacked arrays, and used to construct a compact and highly efficient fiber coupled pump source for Yb:YAG pulsed high-energy class solid-state lasers. The novel configuration is shown to allow repetition rates of 200 Hz at 1 ms pulse duration, at an output power of 130 W per single emitter. The emission of two stacked arrays was then optically combined to realize pump modules that deliver 6 kW peak power (pulse energy 6 J) from a 1.9 mm core diameter fiber, with wall plug efficiency of 50%. This represents a significant improvement in terms of duty cycle and electro-optical efficiency over conventional sources. The pump module has been successfully tested at the Max Born Institute, Berlin during trials for pumping of disk lasers.