We present the first results of the new CO J = (2 − 1) observations toward the central molecular zone (CMZ) using the NANTEN2 telescope at an angular resolution of 100″. Large area coverage of 4° × 2° in l and b and a high angular resolution of 100″ enable us to investigate detailed structures of the molecular gas in the CMZ including peculiar molecular filaments perpendicularly to the Galactic plane to b > |0.5°|. The major components of the CMZ, e.g., Sgr A, Sgr B and Sgr C cloud complexes, show high CO J = (2 − 1)/J = (1 − 0) ratios around 0.9, indicating highly excited conditions of the molecular gas, while the local foreground components show less than 0.4. The molecular filaments show the typical ratios of 0.6–0.7 indicate that they are indeed located in the Galactic center.