Vegetable injury and yield loss has occurred when applying halosulfuron to low-density polyethylene mulch (LDPE) prior to transplanting. Research determined vegetable crop response to halosulfuron applied over LDPE mulch from 1 to 28 d prior to transplanting using (1) temperature effects in aqueous solution in laboratory experiments, (2) analytical evaluation of degradation from LDPE under field conditions, and (3) a field bioassay. Halosulfuron stability was evaluated on a thermal gradient table for temperatures at 10 to 42 C for 15 d. Half-life was inversely related to temperatures ranging from 38.5 d at 20 C to 3.2 d at 42 C, with little to no degradation at temperatures of 11 and 15 C. Analytical data indicated that the field half-life of halosulfuron at 26 or 52 g ha−1 applied to LDPE mulch under dry conditions was 2.6 and 2.8 d, respectively. Given the changes in the microclimate effects at the mulch surface by absorption of solar radiation, daily thermal energy quantified halosulfuron degradation (at the same rates) to be 51 and 55 MJ m−2, respectively. At 21 d after treatment (DAT), 90% of halosulfuron had dissipated from the mulch, with none detectable 35 DAT under dry conditions. When watermelon or yellow crookneck squash was transplanted into mulch previously treated with halosulfuron at 79 g ha−1, plant growth and development were equal to nontreated controls as long as there was a 14 d prior to transplant (DPT) interval accompanied by 13.5 cm of rain, or a 17 DPT interval accompanied by 6.2 cm of rain. However, at 79 g ha−1 applied at 9 or 1 DPT in 2013, and 1 DPT in 2014, halosulfuron injured yellow squash and reduced yield and fruit number. Halosulfuron at 79 g ha−1 applied 1 DPT significantly reduced watermelon yield in 2013, which was confirmed by vine length and plant biomass reductions in 2014. Halosulfuron POST controls Cyperus spp. in mulch vegetable production, but time and rainfall are required for dissipation to occur in order to prevent injury and yield loss.

Sulfonylurea herbicides used in turfgrass—including chlorsulfuron, flazasulfuron, foramsulfuron, halosulfuron, metsulfuron, rimsulfuron, sulfometuron, sulfosulfuron, and trifloxysulfuron—are all weak acids, with disassociation constants ranging from 3.3 to 5.2. Sulfonylureas are used at low rates ranging from 4 to 280 g ha−1. Although these use rates put their soil concentration in parts per billion, they still have residual activity with variable persistence. They have limited susceptibility to soil leaching with weak adsorption to soil clay minerals. Sulfonylurea herbicides used in turfgrass have variable soil organic matter adsorption, which is soil dependent. The persistence and activity of these sulfonylureas are affected by soil pH. At soil pH of 7.0 and greater, some of these sulfonylurea herbicides tend to persist for longer periods with half-lives extending into years rather than days. In normal use patterns with soil pH of 7.0 and less, dissipation occurs via chemical hydrolysis and microbial degradation with half-lives ranging from days to months. Overall, sulfonylurea herbicide adsorption is negatively correlated to increasing pH (increased persistence) and positively correlated to increased organic matter (decreased activity).

Field studies were conducted to examine the dissipation of three soil-applied residual herbicides for bare soil compared with soil under low-density polyethylene (LDPE) mulch in 2003 and 2004. Studies indicated that halosulfuron and S-metolachlor dissipation was more rapid for bare soil than soil under LDPE mulch. Sulfentrazone dissipation from bare soil was equal to soil under LDPE mulch in 2003. However, sulfentrazone dissipation in 2004 was more rapid for soil under LDPE mulch than for bare soil. The order for half-life, defined as time for 50% dissipation (DT50), varied by herbicide and soil exposure. Averaged across 2003 and 2004, metolachlor DT50 was 2 d, halosulfuron 7 d, and sulfentrazone 16 d for bare soil. S-metolachlor DT50 was 4 d, halosulfuron 10 d, and sulfentrazone 13 d for soil under LDPE mulch. Correlation between quantified herbicide dissipation and bioassay for bare soil compared with soil under LDPE mulch in 2004 indicated that assay species root dry weights were negatively correlated with herbicide concentration. Data indicated that S-metolachlor and sulfentrazone bioassays, with oat and cotton, respectively, could be used to assess the level of dissipation for each herbicide.

Field and laboratory studies were conducted to examine herbicide dissipation when applied to low density polyethylene (LDPE) mulch for dry scenarios vs. irrigation. Analytical chemical analysis was used for quantification. In field studies, halosulfuron, paraquat, carfentrazone, glyphosate, and flumioxazin were surface applied to black 32-μm-thick (1.25 mil) LDPE mulch. LDPE mulch harvest began 1 h after treatment (HAT) then continued every 24 h for five consecutive rain-free days after treatment (DAT) to determine the level of herbicide dissipation from the LDPE mulch surface. In a related study, treated LDPE mulch was harvested 1 HAT, then sprinkler irrigation was applied, followed by a sampling five HAT, then the same irrigation and sampling procedure was repeated every 24 h for five consecutive DAT. The order for half-life, as defined as time for 50% dissipation (DT50), varied by herbicide and method of dissipation for dry and irrigated studies. Data indicated that glyphosate and paraquat dissipation was rapid following irrigation. Glyphosate and paraquat DT50 were both 1 h in the irrigated study, but 84 and 32 h for the dry scenario, respectively. This indicated that glyphosate and paraquat could be removed from LDPE mulch with rainfall or irrigation, primarily due to their high water solubility. Halosulfuron and flumioxazin DT50 were 3 and 6 h in the irrigated study, and 18 and 57 h for the dry study, respectively. Carfentrazone DT50 was similar at 28 and 30 h for the irrigated and dry studies, respectively. This indicated that carfentrazone was adsorbed to the LDPE mulch, and irrigation water did not remove it from the LDPE mulch. Results from 14C-herbicide laboratory studies were similar to those from field studies for halosulfuron, glyphosate, paraquat, and flumioxazin.