We use cookies to distinguish you from other users and to provide you with a better experience on our websites. Close this message to accept cookies or find out how to manage your cookie settings.
To save content items to your account,
please confirm that you agree to abide by our usage policies.
If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account.
Find out more about saving content to .
To save content items to your Kindle, first ensure [email protected]
is added to your Approved Personal Document E-mail List under your Personal Document Settings
on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part
of your Kindle email address below.
Find out more about saving to your Kindle.
Note you can select to save to either the @free.kindle.com or @kindle.com variations.
‘@free.kindle.com’ emails are free but can only be saved to your device when it is connected to wi-fi.
‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.
At any moment in time, you can ride a bike with least effort by cycling in first gear. But if you want to ride around the block with least effort, first gear will not be ideal. By failing to distinguish between these two different situations, economists have recommended the worst possible climate change policy to governments. Contrary to their belief, emissions trading will achieve decarbonisation at maximum cost, and minimum speed.
The economics used by governments is based on ideas from the 1870s, when economists adopted the language of science, but not the method. To make the maths easy to solve, they assumed the economy was simple, predictable, and static. Nobody believes these assumptions are true, but they still shape analysis that informs policy. When the economy is complex, uncertain, and changing, this kind of analysis can lead us to bad decisions.
Political factions at Carthage cannot be identified beyond a simple polarity: supporters and opponents of Hannibal’s family, ‘Barcids’ and ‘anti-Barcids’. At Rome, the richer naming system has encouraged prosopographic studies, conjectures about political alliances based on kinship, marriage ties, and shared local origins. But more than temporary existence of such ‘groups’ is doubtful. It is also disputed whether Republican Rome was any sort of democracy: Polybius controversially claimed that tribunes of the plebs were there to do the people’s will. In the second Punic war, where we rely on Livy, elections do not look very democratic, but there is a special and temporary reason for this: demography. Casualties in the 218−216 disasters produced a top-heavy senate for years to come. The trials of the Scipios (180s) do not support the idea of groups but rather exemplify the ruling class’s concern to prevent ambitious individuals from upsetting a competitive equilibrium.
The exchange of various alkylammonium cations from aqueous solution by sodium laponite has been studied. The affinity of the clay for these organic cations was linearly related to the molecular weight, molecular size or chain length of the alkylammonium ions. The affinity for the clay increases regularly with increasing chain length of the primary amines. A comparison of primary, secondary, and tertiary amines, containing the same alkylgroups shows that the affinity increases in the order R1NH3+ < R2NH2+ < R3NH+. These affinity sequences were attributed to important van der Waals contributions and changes in ion hydration states. The thermodynamic excess function, ΔGmE, was calculated and indicated that with respect to the pure homoionic forms the heterogeneous Na+-alkylammonium surface phases were more stable than they would be if the mixing were ideal.
This chapter provides an introduction to mathematical modelling in economics through the study of supply and demand sets, equilibrium and the effect of the imposition of an excise tax.
Halloysite is a common pedogenic clay mineral, often found in young soils developed on volcanic deposits (Dixon, 1989), It is a member of the kaolin group of clays with the same ideal stoichiometric composition as kaolinite [Al2Si2O5(OH)4]. Halloysite, however, often contains water of hydration (i,e., Al2Si2O5(OH)4·nH2O), and is commonly found with a tubular morphology, This “rolling” of halloysite has received a great deal of study because there is no generally agreed upon mechanism for the process and there is no corresponding phenomenon in natural kaolinite (e.g. , Bates et al., 1950; Bailey, 1989; Singh, 1996; Singh and Mackinnon, 1996). The crystal structure of halloysite often shows stacking disorder. This property, combined with a rolled morphology, makes identification by X-ray diffraction (XRD) difficult. The XRD peaks at 7.5, 4.4, and 3.6 Å are often asymmetric with a large width at half peak height (Bailey, 1989).
Contamination of surface and groundwater with glyphosate, used widely on crops to control weeds, can cause severe environmental damage. Processes for glyphosate removal from water bodies have been developed, but few are effective and all are expensive. This objective of the present study was to investigate the use of a layered double oxide as a potentially effective and inexpensive material to remove glyphosate from water. Equilibrium, kinetics, and adsorption mechanisms were evaluated, in addition to the effects of competing anions and temperature on glyphosate adsorption. Up to 95% of glyphosate was removed from a synthetic solution in 50 min by Zn2Al-LDO (layered double oxide in Zn/Al ratio of 2:1) at pH 10. The adsorption isotherms were type L and the Langmuir model best fitted the experimental data, with a qmax value of 191.96 μg mg–1 at 25°C. The XRD pattern did not support the hypothesis of intercalation of glyphosate anions, whereas Fourier-transform infrared and solid-state 13C and 31P magic angle spinning nuclear magnetic resonance confirmed the adsorption of glyphosate anions on the Zn2Al-LDO surface, through carboxylate and phosphonate moiety interactions with end-on and side-on modes. The degree of removal of glyphosate increased with increasing temperature and decreased with increasing concentration of competing anions, with carbonate anions having the most prominent effect on the inhibition of glyphosate adsorption. The adsorption kinetics fitted a pseudo-first order law. Moreover, the intraparticle diffusion model suggested that the adsorption process depends on the formation and thickness of the film at the solution/solid interface.
Differences in equilibration rates among crystals of different sizes may be used to deduce paleofluid changes over time if the crystal-growth mechanism is known. To explore isotopic equilibration rates as a function of illite growth, we studied B-isotope changes during illitization of smectite. Montmorillonite (<2.0 µm SWy-1, K saturated) was reacted with aqueous boric acid (1000 ppm B) at 300°C, 100 MPa in sealed Au capsules (1:1 fluid:mineral ratio). The initial fluid was 0‰ (NBS 951 standard) but after R1 ordering occurred (65 days of reaction) the fluid was changed to −7‰ in order to examine the rate of isotopic re-equilibration. Samples were taken intermittently throughout the experiment. Each aliquot was NH4 exchanged and size separated into fine (<0.2 µm), medium (0.2–2.0 µm) and coarse (>2.0 µm) fractions. The isotopic composition of B in the tetrahedral sheet was then measured for comparison with the predicted equilibrium values.
The fine fraction showed equilibrium isotope ratios within 10 days, indicating that small, newly nucleated crystals precipitate in equilibrium with the fluid under supersaturated, closed conditions. These fine-fraction minerals did not re-equilibrate when the fluid was changed. The medium fraction gradually equilibrated with the initial fluid as illite grew to values >50%, but did not re-equilibrate with the later fluid. The coarse fraction was slow to begin recrystallization, perhaps due to dissolution kinetics of large crystals or the presence of detrital contaminants. However, it showed the fastest rate of isotopic change with crystal growth after R1 ordering. We conclude that at 300°C, the initial B–O bonds formed in illite are stable, and isotopic re-equilibration only occurs on new crystal growth. Therefore, different isotope ratios are preserved in different crystal size fractions due to different rates of crystal growth. Large crystals may reflect equilibrium with recent fluid while smaller crystals may retain isotope compositions reflecting equilibrium with earlier fluids.
Statistical mechanics is the third pillar of modern physics, next to quantum theory and relativity theory. It aims to account for the behaviour of macroscopic systems in terms of the dynamical laws that govern their microscopic constituents and probabilistic assumptions about them. In this Element, the authors investigate the philosophical and foundational issues that arise in SM. The authors introduce the two main theoretical approaches in SM, Boltzmannian SM and Gibbsian SM, and discuss how they conceptualise equilibrium and explain the approach to it. In doing so, the authors examine how probabilities are introduced into the theories, how they deal with irreversibility, how they understand the relation between the micro and the macro level, and how the two approaches relate to each other. Throughout, the authors also pinpoint open problems that can be subject of future research. This title is also available as Open Access on Cambridge Core.
This chapter begins by applying the theory of the firm to the context of a medical practice. The concepts of profit maximization, inputs to production, and outputs from production are all applied to this example. Then the chapter moves on to discuss sources of efficiency in production and specific applications to medical care production. The chapter then develops the basics of supply curves, and how they are interpreted and used, and then brings supply together with demand to describe the basics of equilibrium in an efficient market. The last part of the chapter discusses threats to efficiency in markets, giving a brief overview of the largest sources of difficulty in applying efficient markets to the healthcare context. This sets up the rest of the book: the healthcare sector is filled with problems that make efficient markets unlikely, meaning that understanding the underlying economics is vital.
Utilitarian conservation focuses on a few ecological processes: population regulation in resource-limited systems, succession, predation, and competition. This approach assumes that nature tends toward equilibrium. According to this balance-of-nature mindset, populations are regulated by density-dependent processes. Exponential population growth can generate high numbers quickly, but competition for limiting resources generally keeps populations near the carrying capacity of their environment. In the absence of predation, however, populations may erupt, deplete their food supply, and crash. Similarly, plant associations go through predictable sequences of seral stages culminating in stable climatic climaxes that are able to reproduce themselves indefinitely unless in the absence of disturbances such as fire. Plant associations are groups of interdependent species that all react in the same way to their environment. Utilitarian conservation focuses on keeping populations of economically valuable species such as game animals and commercially harvested trees in balance with their environment.
The human nervous system contains more than 100 billion neurons. Each has a unique function enabling taste, smell, touch, sight, hearing, movement, respiration, cognition, and much more. In the setting of a neurologic emergency, patients may lose these unique capacities. It is the emergency physician’s responsibility to complete a neurologic history and examination to determine the type of deficit and the neuroanatomical location of the abnormality
Duncan Black, like Adam Smith before him, was trained at, and taught at, the University of Glasgow. Like Smith, Black followed the Enlightenment in appreciating the importance of theory and of its empirical applications. Black sought to apply the ideas of a schedule of preferences and a conception of equilibrium, to politics, as Smith had done in economics. Black believed that his median voter theorem could generalize to a theory of politics, much as Smith’s contributions did for market economics. Black did not complete that generalization, but William Riker did offer a theory of institutional politics, designed to complete Black’s project.
Chapter 3 turns to the determinants of the supply of goods and services and to the way in which the “forces” of demand and supply determine prices and the quantities exchanged. Via the use of simple models, economists explain generalizations concerning how the quantities of goods and services supplied respond to prices. The accounts of demand in chapter 2 and supply in this chapter take prices as given, and additional modeling is needed to explain how supply and demand are equilibrated and what properties market equilibria possess. This chapter pulls together the discussions of the first three chapters to offer a general sketch of the causal structure and basic principles of mainstream economics. It takes issue with the view, which used to be dominant, that general equilibrium theory is the fundamental theory of contemporary economics. What I call “equilibrium theory,” not general equilibrium theory, is fundamental.
The economics used by governments is based on ideas from the 1870s, when economists adopted the language of science, but not the method. To make the maths easy to solve, they assumed the economy was simple, predictable, and static. Nobody believes these assumptions are true, but they still shape analysis that informs policy. When the economy is complex, uncertain, and changing, this kind of analysis can lead us to bad decisions.
At any moment in time, you can ride a bike with least effort by cycling in first gear. But if you want to ride around the block with least effort, first gear will not be ideal. By failing to distinguish between these two different situations, economists have recommended the worst possible climate change policy to governments. Contrary to their belief, emissions trading will achieve decarbonisation at maximum cost, and minimum speed.
This chapter develops the water balance equation and its solutions for various inputs to study temporal water fluctuations in the groundwater system. This equation is applied to a field aquifer for estimating the parameters and recharge. Subsequently, the well-mixed model for the solute and its analytical solutions for various input forms are developed. Further, the chapter discusses the hydraulic response, water retention, and chemical response time, pertinent to understanding energy propagation, solute advection, and mixing concepts. The application of the groundwater model to highway deicing salt application follows. The model for reactive chemical solutions comes next, considering chemical decay, first-order equilibrium, and nonequilibrium reactions. Their effects on solution output are discussed. We then introduce the Monte Carlo simulation, sensitivity analysis, and first-order analysis based on the well-mixed model to address uncertainty in the model outputs due to unknown parameters and inputs. Finally, its application to groundwater reservoirs’ effects on buffering acid rains in a lake is presented.
The new Constitution had existed for a short time before Madison and others became concerned about constitutional interpretations that were expanding the power of the national government. This early dialogue about federalism centered on what each state viewed as undesirable equilibrium: either forces that would weaken the relative authority of states or forces that would diminish national authority. Secretary of the Treasury Alexander Hamilton’s financial and economic policies were broad expansions of national powers including assuming Revolutionary War debts and establishing a national bank. Anti-Federalists and others viewed these policies as part of a dangerous trend towards national consolidation that would eventually annihilate the states. Southern states, in particular, thought that without constitutional amendments to constrain the powers of a Northern majority, the South would be unable to protect slavery. When Virginia’s legislature passed the nation’s first interposition resolutions and a memorial in 1790 to sound the alarm to other states and Congress, it faced Federalist criticism that it was illegitimately intruding into the federal government’s sphere.
Chapter 6 unpacks the idea of reflexivity in judicial decision-making and its relationship with coherence. The chapter’s thesis is that coherence in legal reasoning and one’s commitment to reflexivity are intrinsically related notions. Reflexivity in adjudication is conducive towards coherence and, by extension, the degree of a decision-maker’s reflexivity can act as a useful indicator (though not a determinant) of the decision’s overall coherence. The chapter proceeds in two steps in particular. Firstly, it describes reflexivity as an overall desirable disposition for adjudicators to have. It identifies key components of reflexivity in practical decision-making, considers potential critiques, and ultimately establishes reflexivity as an indicator of coherence. Secondly, the chapter attempts to place the discussion in a practical context by way of a case study on the reflective thinking likely at play behind decisions addressing nationality planning activities by foreign investors. In so doing, the chapter also reviews instances where an arguably inadequate process of reflection may have negatively affected the overall coherence of an arbitral decision.