We show that it is possible to construct a class of entropicschemes for the multicomponent Euler system describing a gas or fluidhomogeneous mixture at thermodynamic equilibrium by applying a relaxation technique. Afirst order Chapman–Enskog expansion shows that the relaxed systemformally converges when the relaxation frequencies go to the infinitytoward a multicomponent Navier–Stokes system with the classical Fick andNewton laws, with a thermal diffusion which can be assimilated to a Soret effect in the case of a fluid mixture,and with also a pressure diffusion or a density diffusion respectively for a gas or fluid mixture. We also discuss on the link between the convexity of the entropies of each species and the existence of the Chapman–Enskog expansion.
