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5. On a Glass Digester in which to Heat Substances under Pressure

Published online by Cambridge University Press:  15 September 2014

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Extract

The objections to the use of sealed tubes are known to every practical chemist, and are a serious drawback to their employment. The chief of these are the time expended in the manufacture of the tubes, the amount of skill in glass-blowing required, the danger experienced in opening them, and above all, the fact that only a small quantity of material can be heated at one operation. Moreover, the same tube can seldom be used for more than three or four experiments, as each time it is sealed up its neck must be drawn out, and its length thus considerably decreased. These disadvantages were especially felt by me whilst preparing bromacetic acid, which was required in considerable quantities, and where as many as half a dozen tubes of bromine and acetic acid had to be heated before 100 grammes of the acid could be obtained. To obviate these objections I have had an apparatus constructed, which consists of a cylinder of glass, the walls of which are about half an inch thick. Its length is fifteen inches, its external diameter three inches, and its capacity about 600 cubic centimetres. At one end it is drawn out to a tube, whose aperture is only about one-sixth of an inch in diameter, though its walls are as thick as the rest of the apparatus. Originally this tube was provided with a stopcock, but at Professor Brown's suggestion, I have substituted a glass plate, which is ground fiat, and accurately adapted to the top of the tube.

Type
Proceedings 1875-76
Copyright
Copyright © Royal Society of Edinburgh 1878

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