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Spitzer spectroscopy of unusual hydrocarbons in cool radiative environments

Published online by Cambridge University Press:  01 February 2008

G. C. Sloan*
Affiliation:
Cornell University, Space Sciences 108, Ithaca, NY 14853-6801 email: [email protected]
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Abstract

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The Spitzer Space Telescope has discovered several objects with unusual spectra, where the emission features from polycyclic aromatic hydrocarbons (PAHs) are shifted to longer wavelengths than normally observed. Previously, only two of these class C PAH spectra had been identified. The new and larger sample reveals that PAHs emit at longer wavelengths when processed by cooler radiation fields. Limited laboratory data show that samples with mixtures of aromatic and aliphatic hydrocarbons produce emission features at longer wavelengths than purely aromatic samples. The aliphatic bonds are more fragile and would only survive in cooler radiation fields. In harsher radiation fields, the aliphatics attached to the aromatic hydrocarbons are destroyed.

Type
Contributed Papers
Copyright
Copyright © International Astronomical Union 2008

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