Ultra-luminous infrared galaxies (ULIRGs) are extreme in many ways. The major mergers trigger star formation at very high rates that cause the ISM to be dominated by infrared (IR) photons. We show the ammonia spectra toward the two cores of Arp 220, the nearest ULIRG, in three Very Large Array (VLA) bands (Ku, K, Ka). Typical decay times of the non-metastable transitions ∼ 100 s and are therefore usually difficult to observe. The FIR excitation of Arp 220, however, shows that non-metastable states are widely populated up to a limiting energy of ∼ 1500 K. We assume that this atypical ammonia spectrum is due to the strong FIR field that re-excites the ammonia molecule on timescales much shorter than the already short decay times. The resulting level population causes a break-down of the typical assumptions made for the use of ammonia as a molecular thermometer.