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Using Linear Free Energy Relationship to Predict the Stability Constants of Aqueous Complexes of Metal-Organic Ligands

Published online by Cambridge University Press:  17 March 2011

Huifang Xu  and
Yifeng Wang
Huifang Xu
Affiliation:
Department of Earth and Planetary Sciences, The University of New Mexico, Albuquerque, New Mexico 87131, [email protected]
Yifeng Wang
Affiliation:
Sandia National Laboratories, Albuquerque, NM 87185, [email protected]
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Abstract

The Sverjensky-Molling linear free energy relationship was originally developed to correlate the Gibbs free energies of formation of an isostrutural family of solid phases to the thermodynamic properties of aqueous cations. In this paper, we demonstrate that the similar relationship also exists between metal complexes and simple metal cations in aqueous solutions. We extend the Sverjensky-Molling relationship to predict the Gibbs free energies of formation or dissociation constants for a family of metal complexes with a given complexing ligand. The discrepancies between the predicted and experimental data are generally less than 1.5 kcal/mol (or one log unit for stability constants). The use of this linear free energy correlation can significantly enhance our ability to predict the speciation, mobility, and toxicity of heavy metals in natural environments. According the obtained results, Gibbs free energies of formation of cations (δG0f, Mn+) can be used as an indicator for the hardness/softness of a metal cation (acid). The higher negative value of a metal cation, the harder acid it will be. It is logical to postulate that the coefficient a*ML characterizes the softness of a complexing ligand (base).

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 824: Symposium CC – Scientific Basis for Nuclear Waste Management XXVIII , 2004 , CC7.9
Copyright
Copyright © Materials Research Society 2004

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