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Time-Resolved Crystallization of GeTe
Published online by Cambridge University Press: 28 February 2011
Abstract
Amorphous thin films of GeTe were irradiated with excimer laser pulses and the subsequent crystallization was investigated utilizing simultaneous transient reflectivity and conductivity measurements. Below a threshold fluence of 15 mJ/cm2 pure thermal behaviour was found. Above that value, nucleation and growth are observed during the cooldown process. Above a fluence of 22 mJ/cm2 the films crystallize to a large degree within 200ns. Between 15 and 22 mJ/cm2 crystallite nuclei are formed (“frustrated crystallization”), and application of a subsequent pulse over areas exposed to this fluence regime leads to extremely fast crystallization (50 ns).
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