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Synthesis of Hybrid Organic-Inorganic Sol-Gel Coatings for Corrosion Resistance

Published online by Cambridge University Press:  10 February 2011

T. L. Metroke ,
R. L. Parkhill  and
E. T. Knobbe
T. L. Metroke
Affiliation:
Department of Chemistry and the Environmental Institute, Oklahoma State University, Stillwater, OK 74078, [email protected]
R. L. Parkhill
Affiliation:
Wright Laboratories, Materials Directorate, Wright Patterson Airforce Base, Dayton, OH
E. T. Knobbe
Affiliation:
Department of Chemistry and the Environmental Institute, Oklahoma State University, Stillwater, OK 74078, [email protected]
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Abstract

1H-13C and 1H- 29Si CP/MAS NMR spectroscopy has been used to characterize the structure of sol-gel derived hybrid materials prepared from 3-glycidoxypropyltrimethoxysilane (GLYMO) and tetraethylorthosilicate (TEOS) as a function of hydrolysis water ratio and organic content. 1H-13C CP/MAS NMR data indicate that the concentration of hydrolysis water (R value) has a fundamental effect on the nature of the acid-catalyzed hydrolysis and ring opening products. 1H-29Si CP/MAS NMR data suggest that for low R values, the ormosils are composed of a silica network with epoxide groups randomly dispersed throughout. At high R values, epoxide functionalities were found to coat the surfaces of dense silica particles. Salt spray analysis indicates that the corrosion resistance behavior of thin films derived from GLYMOTEOS ormosils decreases as the concentration of hydrolysis water increases and improves as the organic content in the film increases. These observations can be related to the underlying thin film structure.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 576: Symposium DD – Organic/Inorganic Hybrid Materials II , 1999 , 293
Copyright
Copyright © Materials Research Society 1999

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References

REFERENCES

1. Suzuki, I., Corrosion-Resistant Coatings Technology (Marcell Dekker, New York, 1989), p. 172.10.1201/9781482293258Google Scholar
2. Blue Ribbon Advisory Report, Wright Laboratory, Wright Patterson Airforce Base, Dayton, OH, 1995.Google Scholar
3. Etienne, P., Denape, J., Paris, J. Y., Phalippou, J., and Sempere, R., J. Sol-Gel Sci. Techn. 6, 287 (1996).10.1007/BF00402701Google Scholar
4. Chu, L., Daniels, M. W., and Francis, L. F., Chem. Mater. 9, 2577 (1997).10.1021/cm9702880Google Scholar
5. Kasemann, R. and Schmidt, H., New J. Chem. 18, 1117 (1994).Google Scholar
6. Kasemann, R., Schmidt, H. K., and Wintrich, E. in Better Ceramics Through Chemistry VI, edited by Brinker, C. J., Clark, D. E., and Ulrich, D. R. (Mater. Res. Soc. Proc. 346, Pittsburg, PA, 1994) p. 915.Google Scholar
7. Schmidt, H., J. Non-Cryst. Solids 112, 419 (1989).10.1016/0022-3093(89)90565-6Google Scholar
8. Jay, R. R., Anal. Chem. 36, 667 (1964).10.1021/ac60209a037Google Scholar
9. Husing, N., Schwertfeger, F., Tappert, W., and Schubert, U., J. Non-Cryst. Solids 186, 37 (1995).10.1016/0022-3093(95)00031-3Google Scholar
10. Glaser, R. J., Wikes, G. L., and Bronnimann, C. E., J. Non-Cryst.Solids 3, 73 (1989).10.1016/0022-3093(89)90320-7Google Scholar
11. Riegel, B., Plittersdorf, S., Kiefer, W., Hfising, N., Schubert, U., J. Molec. Struct. 410–411, 157 (1997).Google Scholar
12. De Witte, B. M., Commers, D., Uytterhoeven, J. B., J. Non-Cryst. Solids 202, (1996) 35.10.1016/0022-3093(96)00171-8Google Scholar