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Structure Control of Bioactive Titanate Nanomesh Layers Fabricated on Laser Irradiated Ti-based Bulk Metallic Glass using Hydrothermal-Electrochemical Method

Published online by Cambridge University Press:  28 March 2011

Sayaka Maruyama ,
Naota Sugiyama ,
Masahiro Yoshimura ,
Togo Shinonaga ,
Masahiro Tsukamoto ,
Nobuyuki Abe ,
Takeshi Wada ,
Xinmin Wang ,
Akihisa Inoue  and
Kiyoshi Okada
...Show all authors
Sayaka Maruyama
Affiliation:
Materials and Structures Laboratory, Tokyo Institute of Technology, Yokohama, Kanagawa, Japan
Naota Sugiyama
Affiliation:
Materials and Structures Laboratory, Tokyo Institute of Technology, Yokohama, Kanagawa, Japan
Masahiro Yoshimura
Affiliation:
Materials Science and Engineering, National Cheng Kung University, Tainan, Taiwan
Togo Shinonaga
Affiliation:
Joining and Welding Research Institute, Osaka University, baraki, Osaka, Japan
Masahiro Tsukamoto
Affiliation:
Joining and Welding Research Institute, Osaka University, baraki, Osaka, Japan
Nobuyuki Abe
Affiliation:
Joining and Welding Research Institute, Osaka University, baraki, Osaka, Japan
Takeshi Wada
Affiliation:
Institute of Materials Research, Tohoku University, Miyagi, Japan
Xinmin Wang
Affiliation:
Institute of Materials Research, Tohoku University, Miyagi, Japan
Akihisa Inoue
Affiliation:
Institute of Materials Research, Tohoku University, Miyagi, Japan
Kiyoshi Okada
Affiliation:
Materials and Structures Laboratory, Tokyo Institute of Technology, Yokohama, Kanagawa, Japan
Nobuhiro Matsushita
Affiliation:
Materials and Structures Laboratory, Tokyo Institute of Technology, Yokohama, Kanagawa, Japan
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Abstract

The surface of Ti-based bulk metallic glass (BMG) was irradiated by the femto-second laser and microgrooves were formed on the surface. The titanate nanomesh layers were fabricated on the micro-grooved BMG surface by hydrothermal-electrochemical (H-E) treatment changing the conditions of the concentration of electrolyte solution (0 and 5 M) and applying current density (0-200 mA/cm2). The bone-inducing capacity of the samples with different H-E treatment was confirmed by soaking them in a simulated body fluid for 12 days. The H-E treatment in higher concentration 5 M NaOH aq. and applying higher current density above 0.5 mA/cm2 exhibited excellent bioactivity inducing large hydroxyapatite crystallites.

Keywords

electrochemical synthesishydrothermalnanostructure
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1316: Symposium QQ – Nanofunctional Materials, Nanostructures and Nanodevices for Biomedical Applications II , 2011 , mrsf10-1316-qq06-17
Copyright
Copyright © Materials Research Society 2011

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References

REFERENCES

1. Tanner, L. E. and Ray, R., Scr. Metall. 11, 783–789 (1977)Google Scholar
2. POLK, D. E., CALKA, A. and GIESSEN, B. C., Acta Matell. 26, 1097–1103 (1978)Google Scholar
3. AMIYA, K., NISHIYAMA, N., INOUE, A. and MASUMOTO, T., Mater Sci Eng A 179, 692 (1994)Google Scholar
4. Kim, Y. C., Bae, D. H., Kim, W. T. and Kim, D. H., J. Non-Cryst. Solids 325, 1–3, 242-250 (2003)Google Scholar
5. Park, J. M., Kim, Y.C., Kim, W.T. and Kim, D.H., Mater. Trans. 45, 2, 595-598 (2004)Google Scholar
6. Morrison, M. L., Buchanan, R. A., Peker, A., Liaw, P. K., Horton, J. A., J. Non-Cryst. Solids 353, 22–23, 2115-2124 (2007)Google Scholar
7. Sugiyama, N. and Yoshimura, M., Mater. Sci. Eng. B 161, 1–3, 31-35 (2009)Google Scholar
8. Sugiyama, N., Xu, H. Y., Onoki, T., Hoshikawa, Y., Watanabe, T., Matsushita, N., Wang, X., Qin, F. X., Fukuhara, M., Tsukamoto, M., Abe, N., Komizo, Y., Inoue, A. and Yoshimura, M., Acta. Biomater. 5, 1367–1373 (2009)Google Scholar
9. Momma, C., Chichkov, B. N., Nolte, S., Alvensleben, F. V., Tunnermann, A., Welling, H., Opt. Commun. 128, 101–9 (1996)Google Scholar
10. Chichkov, B. N., Momma, C., Nolte, S., Alvensleben, F. V., Tunnermann, A., Appl. Phis. A 63, 2, 109-115 (1996)Google Scholar
11. Tsukamoto, M., Asuka, K., Nakano, H., Hashida, M., Katto, M., N.Abe, M. Fujita, Vacuum 80, 1346–1350 (2006)Google Scholar
12. Inoue, A., Mater. Trans. JIM 36, 7, 866-875 (1995)Google Scholar
13. Kokubo, T. and Takadama, H., Biomaterials 27, 2907–2915 (2006)Google Scholar
14. Kim, H. M., Miyaji, F., Kokubo, T., Nakamura, T., J. Mater. Sci. Mater. Med. 8, 341–347 (1997)Google Scholar