Hostname: page-component-78c5997874-94fs2 Total loading time: 0 Render date: 2024-11-17T18:13:59.686Z Has data issue: false hasContentIssue false
  • English
  • Français

Solid State Synthesis and Characterization of Tin-Based Low-Dimensional Materials

Published online by Cambridge University Press:  11 February 2011

Tolulope O. Salami  and
Scott R. J. Oliver
Tolulope O. Salami
Affiliation:
Department of Chemistry, State University of New York at Binghamton, Binghamton, New York 13902–6016, U.S.A.
Scott R. J. Oliver
Affiliation:
Department of Chemistry, State University of New York at Binghamton, Binghamton, New York 13902–6016, U.S.A.
Get access

Abstract

We report the synthetic conditions, physical properties and potential applications of late group 14 metal (Sn) 0D, 1D, 2D and 3D extended materials. The structures are primarily neutral chain and anionic layered compounds. The latter are charge-balanced by ammonium cations, as in and BING-7 [Sn(C2O4)F-] [NH4+] and BING-8 [Sn(PO4H)F-] [NH4+]. The neutral layered compound and chain compounds BING-1 [Na4Sn4(C2O4)F6], BING-2 [KSn(C2O4)F] and BING-4 [Sn(C2O4)(C5H5N)] have also been synthesized solvothermally. Thermogravimetric analysis (TGA) under nitrogen and in-situ variable temperature X-ray diffraction show that the materials decompose in the 200°C to 300°C range to more stable phases. Nuclear magnetic resonance (NMR) was used to monitor the ion-exchange properties of some of the materials. The intercalation properties of these materials are still being investigated.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 755: Symposium DD – Solid-State Chemistry of Inorganic Materials IV , 2002 , DD6.19
Copyright
Copyright © Materials Research Society 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Bowes, C.L. and Ozin, G.A., Adv. Mater. 8, 13 (1996).Google Scholar
2 Kresge, C.T., Leonowicz, M.E., Roth, W.J., Vartuli, J.C. and Beck, J.S., Nature 339, 710 (1992).Google Scholar
3 Salami, T. O., Marouchkin, K., Zavalij, P. Y. and Oliver, S. R. J, Chem. Mater. 14, 4851–4857 (2002).Google Scholar
4 Tran, D. T., Zavalij, P. Y. and Oliver, S. R. J., J. Am. Chem. Soc. 124, 3966 (2002).Google Scholar
5 Salami, T. O., Zavalij, P. Y. and Oliver, S. R. J, Acta Cryst. E57, m111 (2001).Google Scholar
6 Salami, T. O., Zavalij, P. Y. and Oliver, S. R. J, Acta Cryst. E57, i49 (2001).Google Scholar
7 Lansky, D. E., Zavalij, P. Y. and Oliver, S. R. J Acta Cryst. C57, 1051 (2001).Google Scholar
8 Ayyapan, S., Nataranjan, A. K. and Rao, C.N.R. Chem. Mater. 10, 3746 (1998).Google Scholar
9 Jiang, T. and Ozin, G. A., J. Mater. Chem. 8, 5, 1099 (1998).Google Scholar
10 Halasyamani, P., Willis, M. J, Stern, C. L, Lundquist, P. M, Wong, G.K. and Poeppelmeier, K.R., Inorg. Chem. 35, 1367 (1996);Google Scholar
Halasyamani, P., Heier, K. R., Norquist, A. J, Stern, C. L. and Poeppelmeier, K. L, Inorg. Chem., 37, 369, (1998).Google Scholar