Hostname: page-component-586b7cd67f-r5fsc Total loading time: 0 Render date: 2024-11-23T03:44:30.748Z Has data issue: false hasContentIssue false
  • English
  • Français

Raman Studies Of LiMn2O4 Films Grown by Laser Ablation

Published online by Cambridge University Press:  10 February 2011

M.A. Camacho-Lopez ,
L. Escobar-Alarcon ,
E. Haro-Poniatowski  and
C. Julieni
M.A. Camacho-Lopez
Affiliation:
LMDH, UMR 7603, Université Pierre et Marie Curie, 4 place Jussieu, case 86 75252 Paris cedex 05, France Laboratorio de Optica Cuantica, Universidad Autónoma Metropolitana lztapalapa Apdo., Postal 55-534, México DF 09340, México
L. Escobar-Alarcon
Affiliation:
Departamento de Fisica, Instituto Nacional de Investigaciones Nucleares Apdo., Postal 18-1027, México DF 11801, México
E. Haro-Poniatowski
Affiliation:
Laboratorio de Optica Cuantica, Universidad Autónoma Metropolitana lztapalapa Apdo., Postal 55-534, México DF 09340, México
C. Julieni
Affiliation:
LMDH, UMR 7603, Université Pierre et Marie Curie, 4 place Jussieu, case 86 75252 Paris cedex 05, France
Get access

Abstract

Polycrystalline thin films of lithium manganese oxide have been grown using the pulsed-laser deposition (PLD) technique. Films of LiMnO2O4, were deposited onto Si substrates heated at temperature lower than 300°C from a sintered composite target (LiMn2O4+Li2O) irradiated with a Nd:YAG laser. The structural characterizations of these films have been carried out by Raman scattering spectroscopy which probe the local environment of cations in the LiMn2O4 framework. Raman spectra of PLD LiMn2O4 films have been investigated as a function of various growth conditions, i.e. substrate temperature, partial oxygen pressure in the deposition chamber, and target composition.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 617: Symposium J – Laser-Solid Interactionsfor Materials Processing , 2000 , J3.17
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 Ohzuku, T., in: Lithium Batteries, edited by Pistoia, G. (Elsevier, Amsterdam, 1993), p. 239.Google Scholar
2 Julien, C., Rougier, A., Nazri, G.A., Mat. Res. Soc. Symp. Proc. 453 (1997) 647.Google Scholar
3 Gummow, R.J., deKock, A., Thackeray, M.M., Solid State Ionics 69 (1994) 59.Google Scholar
4 Shokoohi, F.K., Tarascon, J.M., Wilkens, B.J., Guyomard, D., Chang, C.C., J. Electrochem. Soc. 139 (1992) 1845 Google Scholar
5 Liquan, C. and Schoonman, J., Solid State Ionics 67 (1994) 17.Google Scholar
6 Hwang, K.H., Lee, S.H., Joo, S.K., J. Electrochem. Soc. 141 (1994) 3296.Google Scholar
7 Miura, T., Kishi, T, Mat. Res. Soc. Symp. Proc. 393 (1995) 69.Google Scholar
8 Antaya, M., Dahn, J.R., Preston, J.S., Rossen, E., Reimers, J.N., J. Electrochem. Soc. 140 (1993) 575.Google Scholar
9 Chen, C., Kelder, E.M., Put, P.J.J.M. van der, Schoonman, J., J. Mater. Chem. 6 (1996) 765.Google Scholar
10 Ginley, D.S., Perkins, J.D., McGraw, J.M., Parilla, P.A., Fu, M.L., Rogers, C.T., Mat. Res. Soc. Symp. Proc. 496 (1998) 293.Google Scholar
11 Striebel, K.A., Deng, C.Z., Wen, S.J., Cairns, E.J., J. Electrochem. Soc. 143 (1996) 1821.Google Scholar
12 Rougier, A., Striebel, K.A., Wen, S.J., Cairns, E.J., J. Electrochem. Soc. 145 (1998) 2975.Google Scholar
13 Morcrette, M., Barboux, P., Perriere, J., Brousse, T., Solid State Ionics 112 (1998) 249.Google Scholar
14 White, W.B., Angelis, B.A. De, Spectrochim. Acta 23A (1967) 985.Google Scholar
15 Julien, C., Perez-Vicente, C., Nazri, G.A., Ionics 2 (1996) 1.Google Scholar
16 Julien, C., Massot, M., Perez-Vicente, C., Haro-Poniatowski, E., Nazri, G.A., Rougier, A., Mat. Res. Soc. Symp. Proc. 496 (1998) 415.Google Scholar
17 Escobar-Alarcon, L., Haro-Poniatowski, E., Jimenez-Jarquin, J., Massot, M. and Julien, C., Mat. Res. Soc. Symp. Proc. 548 (1999) 223.Google Scholar