Hostname: page-component-586b7cd67f-t7czq Total loading time: 0 Render date: 2024-11-25T17:43:59.288Z Has data issue: false hasContentIssue false

Plasma Surface Modification of Medical-Grade Ultra-High Molecular Weight Polyethylene for Improved Tribological Properties

Published online by Cambridge University Press:  15 February 2011

C.M. Klapperich
Affiliation:
Department of Mechanical Engineering, University of California, Berkeley, CA 94720
K. Komvopoulos
Affiliation:
Department of Mechanical Engineering, University of California, Berkeley, CA 94720
L. Pruitt
Affiliation:
Department of Mechanical Engineering, University of California, Berkeley, CA 94720
Get access

Abstract

Ultra-high molecular weight polyethylene (UHMWPE) is the principal material used to replace damaged cartilage in total joint replacement surgeries. This publication presents preliminary results from a new class of surface treatments to modify the surface chemistry and microstructure of UHMWPE under controlled processing conditions. Radio frequency plasmas were used to lightly crosslink the subsurface of UHMWPE and to modify the surface chemical state through the attachment of low-surface-energy fluorocarbon groups. A pin-on-disk apparatus was used to slide CoCrWNi pins with spherical tips on polished disks of plasma- treated and untreated UHMWPE immersed in a bath of preserved bovine serum. The wear resistance and surface chemical composition of tested specimens were characterized by surface profilometry and X-ray photoelectron spectroscopy (XPS), respectively. Changes in the surface hydrophobicity due to plasma treatment were evaluated using contact angle measurements. The prospect of surface plasma treatment in orthopedic applications is elucidated in the context of the obtained friction, wear, distilled water contact angle, and XPS results.

Type
Research Article
Copyright
Copyright © Materials Research Society 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Lewis, G., J. Biomed. Mater. Res. 38, 55 (1997).Google Scholar
2. Klapperich, C., Komvopoulos, K., and Pruitt, L., J. Tribol. 121 (1999), in press.Google Scholar
3. Kurtz, S.M., Pruitt, L., Jewett, C.W., Crawford, R.P., Crane, D. J., Roberts, D., and Edidin, A. A., J. Arthroplasty, (1999), in press.Google Scholar
4. McKellop, H., Shen, F.-W., and DiMaio, W., MRS Fall Meeting Abstracts, 352 (1997).Google Scholar
5. Muratoglu, O., O'Connor, D., Bragdon, C., Jasty, M., and Harris, W., MRS Fall Meeting Abstracts, 353 (1997).Google Scholar
6. Baker, D., Hastings, R., and Pruitt, L., J. Biomed. Mater. Res. (1999), in press.Google Scholar
7. Ratner, B. D. and McElroy, B.J., Spectroscopy in the Biomedical Sciences, Gendreau, R.M., ed., CRC Press, Boca Raton, FL (1986).Google Scholar