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Published online by Cambridge University Press: 25 February 2011
We have studied the photoelectronic properties of pipi... multilayers made of a-SiC:H p-layers (∼ 100Å) alternating with a-Si:H i-layers (500Å to 4000Å). A large enhancement in d.c. coplanar photoconductivity (more than an order of magnitude) over that of bulk a-Si:H was observed with decreasing i-layer thickness of the multilayer. On the other hand, the ambipolar diffusion length was observed to decrease with decreasing i-layer thickness. These observations can be explained by the effect of charge separation due to the strong built-in electric field in the i-layer. The insertion of an ultrathin SiC layer at the p/i interface is shown to appreciably reduce the built-in field which may be directly related to the observed decrease in fill factor when such a buffer layer is used in a solar cell.