Hostname: page-component-78c5997874-g7gxr Total loading time: 0 Render date: 2024-11-04T21:52:00.239Z Has data issue: false hasContentIssue false
  • English
  • Français

New Approaches to Chemical Bath Deposition of Chalcogenides

Published online by Cambridge University Press:  10 February 2011

Paul O’brien ,
Markus R. Heinrich ,
David J. Otway ,
Odile Robbe ,
Alexander Bayer  and
David S. Boyle
Paul O’brien
Affiliation:
1. Department of Chemistry, and The Manchester Materials Science Centre, Manchester University, Oxford Rd, Manchester, M13 9P, UK Email addresses: [email protected]
Markus R. Heinrich
Affiliation:
2. Department of Chemistry, Imperial College of Science, Technology and Medicine, Exhibition Road, London, SW7 2AZ, UK
David J. Otway
Affiliation:
2. Department of Chemistry, Imperial College of Science, Technology and Medicine, Exhibition Road, London, SW7 2AZ, UK Email addresses: [email protected];
Odile Robbe
Affiliation:
2. Department of Chemistry, Imperial College of Science, Technology and Medicine, Exhibition Road, London, SW7 2AZ, UK
Alexander Bayer
Affiliation:
2. Department of Chemistry, Imperial College of Science, Technology and Medicine, Exhibition Road, London, SW7 2AZ, UK
David S. Boyle
Affiliation:
3. Department of Physics, Science Laboratories, University of Durham, South Road, Durham, Email addresses: DHI [email protected]
Get access

Abstract

We have been studying new approaches to conventional Chemical Bath Deposition (CBD) of chalcogenide containing materials, using continuous circulation and replenishment of CBD solution over a heated substrate. Crystalline thin films produced by this method offer potential for use in solar cell devices or other optoelectronic applications. Films of CdS, ZnS and the ternary material CdxZn1−xS have been deposited on TO-glass substrates. In this paper we demonstrate our approach for the deposition of CdS films. These have been characterized by XPS, SEM, XRD and UV/vis spectroscopy and shown to be good quality. The films have been used to fabricate Au/CdTe/CdS/TO-glass solar cells of efficiency 10.1% under AMl.5 illumination.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 606: Symposium NN – Chemical Processing of Dielectrics, Insulators & Electronic Ceramics , 1999 , 199
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 Zweibel, K., Solar Energy Materials and Solar Cells 59, 1 (1999).Google Scholar
2 Bonnet, D., Meyers, P., Journal of Materials Research 13, 2740 (1998).Google Scholar
3 Patterson, M. S., Turner, A. K., Sadeghi, M., Marshall, R. J., Proc. 12th European Photovoltaic Solar Energy Conf. 950 (1994).Google Scholar
4 O’Brien, P. and McAleese, J., J. Mater. Chem 8, 2309 (1998).Google Scholar
5 Jones, A. C. and O'Brien, P., CVD of Compound Semiconductors; Precursor Synthesis, Development and Applications, VCH, Weinheim, (1997).Google Scholar
6 Lincot, D., Actualite Chimique, p.23 (1999).Google Scholar
7 Stoev, M. and Katerski, K., J. Mater. Chem. 6, 377 (1996).Google Scholar
8 O'Brien, P. and Saeed, T., J. Crystal Growth 158, 497 (1996).Google Scholar
9 Alamri, S. N. A., PhD Thesis, University of Durham 46 (1999).Google Scholar