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Metal Electroplating of Three Dimensional (3D) Electrode in Electrolyte-less Dye Sensitized Solar Cells (ELDSC)

Published online by Cambridge University Press:  23 March 2012

Duen Yang Ong ,
Meng Keong Lim ,
Ziyu Jin ,
Chee Lip Gan ,
Kam Chew Leong  and
C. C. Wong
Duen Yang Ong
Affiliation:
School of Materials Science and Engineering, Nanyang Technological University, Nanyang Avenue 639798, Singapore. GLOBALFOUNDRIES Singapore Private Limited, 60 Woodlands Industrial Park D Street 2 738406, Singapore.
Meng Keong Lim
Affiliation:
GLOBALFOUNDRIES Singapore Private Limited, 60 Woodlands Industrial Park D Street 2 738406, Singapore.
Ziyu Jin
Affiliation:
School of Materials Science and Engineering, Nanyang Technological University, Nanyang Avenue 639798, Singapore.
Chee Lip Gan
Affiliation:
School of Materials Science and Engineering, Nanyang Technological University, Nanyang Avenue 639798, Singapore.
Kam Chew Leong
Affiliation:
GLOBALFOUNDRIES Singapore Private Limited, 60 Woodlands Industrial Park D Street 2 738406, Singapore.
C. C. Wong*
Affiliation:
School of Materials Science and Engineering, Nanyang Technological University, Nanyang Avenue 639798, Singapore.
*
*Corresponding author: Email: [email protected]; Tel: +65 67904595; Fax: +65 6790 9081
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Abstract

The first Electrolyte-less dye sensitized solar cell (ELDSC) is proposed with the architecture of FTO-TiO2-dye-metal. In the ELDSC design, the most significant contact is the TiO2-dye-metal interface, whereby the metal electrode acts as the charge replenishment layer as well as the external electrode. In previous work, ELDSC has an inferior Fill Factor (FF) due to insufficient metal coverage from top-down physical vapor deposition. In this work, a three dimensional (3D) metal network plated through the mesoporous TiO2 network is achieved through bottom-up metal electroplating. This study focuses on the characteristics of electro deposition onto insulating planar TiO2 as well as mesoporous TiO2 network. For planar TiO2, gold (Au) islands form readily, becoming worm-like structures as they coalesce, subsequently becoming a continuous layer. (The plated metal on the insulating TiO2 layer is made possible by plane defects within the insulator layer that serve as the conductive supply path.) In contrast, electroplating carried out on a FTO-planar TiO2-mesoporous TiO2 substrate results in a 3D Au network within the mesoporous TiO2, where Au cords were observed as the connections among Au islands. This study demonstrates that a continuous metal layer can be electroplated onto an insulating TiO2 layer, borrowing its intrinsic planar defect network. Further, applying the same principle, a 3D metal network can be formed within mesoporous TiO2.

Keywords

Auelectrodepositionphotovoltaic
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1390: Symposium H/I – Organic Photovoltaics–Materials to Devices , 2012 , mrsf11-1390-h03-60
Copyright
Copyright © Materials Research Society 2012

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References

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