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Hybrid Gels and Nanoscale Chemistry for Optical Applications

Published online by Cambridge University Press:  10 February 2011

J-P. Boilot ,
J. Biteau ,
A. Brun ,
F. Chaput ,
T. Dantas De Morais ,
B. Darracq ,
T. Gacoin ,
K. Lahlil ,
J-M. Lehn  and
Y. Levy
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J-P. Boilot
Affiliation:
Laboratoire de Physique de la Matiére Condenéde, CNRS UMR 7643, Ecole Polytechnique. 91128 Palaiseau Cedex, France.
J. Biteau
Affiliation:
Laboratoire de Physique de la Matiére Condenéde, CNRS UMR 7643, Ecole Polytechnique. 91128 Palaiseau Cedex, France.
A. Brun
Affiliation:
Laboratoire Charles Fabry de l'Institut d'Optique, URA CNRS 14, Bât. 503, Université d'Orsay-Paris XI, B.P. 147, 91403 Orsay Cedex, FRANCE.
F. Chaput
Affiliation:
Laboratoire de Physique de la Matiére Condenéde, CNRS UMR 7643, Ecole Polytechnique. 91128 Palaiseau Cedex, France.
T. Dantas De Morais
Affiliation:
Laboratoire de Physique de la Matiére Condenéde, CNRS UMR 7643, Ecole Polytechnique. 91128 Palaiseau Cedex, France.
B. Darracq
Affiliation:
Laboratoire Charles Fabry de l'Institut d'Optique, URA CNRS 14, Bât. 503, Université d'Orsay-Paris XI, B.P. 147, 91403 Orsay Cedex, FRANCE.
T. Gacoin
Affiliation:
Laboratoire de Physique de la Matiére Condenéde, CNRS UMR 7643, Ecole Polytechnique. 91128 Palaiseau Cedex, France.
K. Lahlil
Affiliation:
Laboratoire de Physique de la Matiére Condenéde, CNRS UMR 7643, Ecole Polytechnique. 91128 Palaiseau Cedex, France.
J-M. Lehn
Affiliation:
Collége de France, Chimie des Interactions Moléculaires, UPR CNRS 285, 11 place Marcelin Berthelot, 75231 Paris Cedex 05 (France).
Y. Levy
Affiliation:
Laboratoire Charles Fabry de l'Institut d'Optique, URA CNRS 14, Bât. 503, Université d'Orsay-Paris XI, B.P. 147, 91403 Orsay Cedex, FRANCE.
L. Malier
Affiliation:
Laboratoire de Physique de la Matiére Condenéde, CNRS UMR 7643, Ecole Polytechnique. 91128 Palaiseau Cedex, France.
G-M. Tsivgoulis
Affiliation:
Collége de France, Chimie des Interactions Moléculaires, UPR CNRS 285, 11 place Marcelin Berthelot, 75231 Paris Cedex 05 (France).
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Abstract

A large variety of materials for optical and optoelectronic applications has been developed by trapping active organic molecules and nanocrystals into pure inorganic and hybrid organic- inorganic gels. Concerning optically active molecules, we focus only here on luminescent materials for solid state tunable lasers and light-emitting diodes, and photochromic materials for integrated optics and optical storage. Optical properties can be controlled by changing the nature and the intensity of chemical and steric interactions between the organic system and the solid host matrix. Concerning nanocrystals, we present two approaches for the synthesis of transparent solids based on 1I-VI semiconducting nanoparticles. A first category of materials consists in the dispersion of CdS nanoparticles in sol-gel silica matrices. The luminescence can be controlled by offering an alternative pathway for the recombination of surface trapped carriers. A second group of transparent materials is obtained by considering the CdS nanoparticles not only as the optically active units, but also as the building blocks for the whole solid.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 519: Symposium O – Organic/Inorganic Hybrid Materials , 1998 , 227
Copyright
Copyright © Materials Research Society 1998

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